Can a face insert cut your 3-putt percentage? Odyssey AI-One Milled Putter
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Quasi in-situ observation of the microstructure for the CR specimens (a) before and (b) after EPT; EDS results of (c) point A and (d) point B.
M50 bearing steel has been widely used in the aerospace industry as main shaft bearing in gas-turbine engines due to its excellent elevated temperature performance1. In recent years, with the rapid development of aerospace industry, the demand for high properties of aviation bearing steel is constantly increasing for the sake of adapting to the worse working conditions. Therefore, how to improve the mechanical properties of M50 bearing steel has attracted much attention.
Yang, C. L., Yang, H. J., Zhang, Z. J. & Zhang, Z. F. Recovery of tensile properties of twinning-induced plasticity steel via electropulsing induced void healing. Scr. Mater. 147, 88–92 (2018).
(a) AFM image of the nano-indentation for the specimen with EPT at peak load of 2 mN; (b) Average hardness of the ferrite matrix for the CR specimens without EPT and with EPT. The insert is load-displacement curves at peak loads of 2 mN.
Recently, many researches11,12,13,14 have experimentally proven that the macro cracks can be effectively repaired by electropulsing treatment (EPT) due to the temperature rise and compressive stress. Thus, this crack-healing effect gives us a vision that the combination of CR and EPT may further improve the mechanical properties of M50 bearing steel if the nano-size voids around carbides can be healed as well. However, it is worth noting that the voids resulted from CR process mainly locate around high resistance second-phase (carbides), making the application of EPT to affect the nano-size voids more complicated. Besides, the dislocation entanglement induced by CR may also exert a crucial effect on the void healing.
Finish turning of titanium must be a wet process. High-precision coolant offers significant advantages, particularly as it can be directed to the cutting zone. Photo courtesy of Sandvik Coromant.
Zhou, Y. Z., Zeng, Y., He, G. H. & Zhou, B. L. The healing of quenched crack in 1045 steel under electropulsing. J. Mater. Res. 16, 17–19 (2001).
Tonne added that it’s important for shops to inspect tooling centre height positions frequently. Incorrect cutting heights will result in reduced surface finish quality.
This work was financially supported by National Natural Science Foundation of China (51575414, 51875426), Innovative Research Team Development Program of Ministry of Education of China (No. IRT13087) and 111 Project (B17034).
In order to characterize the distribution of voids in the matrix before and after EPT, the CR specimens without and with EPT were micro-machined and detected by a Zeiss Auriga field emission scanning electron microscopy (FESEM) equipped with a focused ion beam (FIB) and an energy dispersive spectroscopy (EDS). Based on at least eight FIB-SEM micrographs, the distribution of equivalent diameter of voids was measured using Photoshop and Image-pro Plus software. The quasi in-situ observation of the voids was performed in the same field through marking with hardness pits. To investigate the size of carbide particles, the carbides in specimens were extracted by chemical dissolution of the matrix in a modified Berzelius solution15 and then analyzed by a Malvern nano particle size analyzer. Additionally, an FEI tecnai F20 transmission electron microscopy (TEM) was employed to observe the microstructure before and after EPT. The specimens for TEM were prepared by mechanically polishing and then electro-polishing in a twin-jet polisher using a solution of 10% perchloric acid and 90% acetic acid.
"We have seen that many shops are unwilling to change from their current processes, even if it means better finishes," said Kevin Burton, turning product and application specialist, Sandvik Coromant, Mississauga, Ont. "If the certified process uses an uncoated carbide insert, shops may not want to change to a coated or diamond insert because of the extra cost both from a time and financial standpoint. It’s the same with grades. With the new generation of grades out, some look different with different colours even though they typically have the same elements, just different percentages. Yet shops tend to be concerned about the coating being left behind on the surface of the part."
Okitsu, Y., Takata, N. & Tsuji, Y. N. A new route to fabricate ultrafine-grained structures in carbon steels without severe plastic deformation. Scr. Mater. 60, 76–7 (2009).
where \({\rm{\Delta }}{{G}_{dis}}^{{\rm{o}}}\) is the free energy change for carbide dissolution in a current-free system, \({\rm{\Delta }}{{G}_{dis}}^{e}=\frac{{\sigma }_{{matrix}}-{\sigma }_{{carbide}}}{2{\sigma }_{{matrix}}+{\sigma }_{{carbide}}}k{j}^{2}V\) is the energy change due to the passage of pulse current through the specimens22. k is the geometric factor, j is the current density, and V is the volume. The higher conductivity of ferrite matrix (\({\sigma }_{{matrix}} > {\sigma }_{{carbide}}\)) results in \({\rm{\Delta }}{{G}_{dis}}^{e} > 0\), which will cause the carbides to be unstable and facilitate the dissolution of carbides into the ferrite matrix as an driving force. Additionally, for the contribution of \({\rm{\Delta }}{{G}_{dis}}^{{\rm{o}}}\), the interfacial energy contribution plays an important role and can be approached by \({\rm{\Delta }}{{G}_{{dis}}}^{{inter}}=\gamma {V}_{m}\frac{dA}{d{V}_{{carbide}}}\)26. Where y, Vm, A and Vcarbide are the specific interfacial energy, the molar volume of carbide, the surface area between carbide and matrix, and the carbide volume, respectively. It can be inferred that the increased surface to volume ratio of matrix/carbide (especially at the tip region of the deformed carbide) will enhance the interfacial energy contribution to the thermodynamically carbide dissolution. Accordingly, the partial dissolution (Fig. 2) potentially results from the lower thermodynamic dissolution barrier for the deformed carbide with a higher surface to volume ratio of matrix/carbide.
Ben, D. D. et al. Rapid hardening of AISI 4340 steel induced by electropulsing treatment. Mater. Sci. Eng. A. 725, 28–32 (2018).
"One misconception is that turning almost no material on the last pass will improve surface finish," said Tonne. "In most cases, the finishing pass depth should be equal to the radius of the tool used for turning. Using zero-depth passes will often fail."
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The low modulus of elasticity causes greater workpiece springback in these materials. This modularity is one of the material’s strengths, particularly when it comes to structural aerospace components that require that movability quality. However, this makes it a challenge to machine, often resulting in tool vibration, chatter, and poor surface finish.
"Speed is the killer in all materials but very much so in titanium," said Burton. "If you go from uncoated to coated, then your speed can go up. Speed is productivity because your feed per revolution stays the same, but the speed goes up. This allows the feed per minute to increase, which is an advantage. Typically, this can be around a 20 per cent gain in productivity. If a shop goes to, say, a PCD insert for finish turning, there will be an even bigger productivity gain. With coated carbide you can expect 150 to180 SFM but up to 600 with PCD. The gain in productivity is huge."
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Titanium generally is used to produce critical aerospace components and medical devices. It offers a high strength-to-weight ratio and excellent corrosion resistance, which enables it to be used for designs with thin walls.
Figure 1 presents the FIB-SEM micrographs of the CR specimens without and with EPT treatment. As indicated in Fig. 1(a), a large number of voids (marked with yellow arrows) less than 1μm have been introduced after the CR process with a 50% thickness reduction. The microstructure of specimens after EPT is shown in Fig. 1(b), where it can be found that some voids have healed (as marked with green arrows) and the number of voids in the matrix have decreased remarkably after EPT. Meanwhile, the distribution of equivalent diameter of voids is further measured as shown in Fig. 1(c). It can be clearly seen that the diameter of voids significantly decreases after EPT, which thus indicates a clear healing effect. In addition, as marked with blue arrows in Fig. 1(a,b), a substantial number of fine carbide particles can be found in the matrix after EPT, while the carbide sizes in the CR specimens are larger than those in the treated specimens. By means of EDS analysis inserted in Fig. 1(b), the nano-size particle (marked with blue circle) is identified to be Cr-rich carbide.
Garg, A., McNelley, T. R. & Perry, J. L. Analysis of microporosity associated with insoluble carbides in VIM-VAR AISI M-50 steel. Metallography. 20, 89–98 (1987).
Lindsay Luminoso, sr. editor/digital editor, contributes to both Canadian Metalworking and Canadian Fabricating & Welding. She worked as an associate editor/web editor, at Canadian Metalworking from 2014-2016 and was most recently an associate editor at Design Engineering.
"PVD coatings have high temperature resistance and lubricous surface, which reduces built-up edge and heat," said Tonne. "When it comes to inserts, the best shape is round, but it is often not practical due to part shape. C- or W-style inserts offer the best finish with clearance for part features. For negative-type inserts, make sure the top rake is positive. If tight tolerances are required, fully ground inserts can improve outcomes."
Previous studies22,23 have shown that the EPT can lead to the dissolution of second-phase below the thermodynamic dissolution temperature within a very short time. Due to the thermal effect of EPT, the real temperature of the treated specimens may have approached or exceeded the critical thermodynamic dissolution temperature. In the meantime, with the enhance of the athermal effect of EPT, the thermodynamic barrier decreases and then the dissolution behavior of the second phase occurs. In this work, considering that the temperature rise induced by joule heating only reached 532 °C, a temperature far away from the critical dissolution temperature of carbides in M50 bearing steel24, the complete dissolution of carbides will not be expected. However, the refinement behavior of carbides in the matrix are surprisingly discovered (Fig. 3), which have been rarely reported so far and will be further discussed.
Kemp, I. P., Pollard, G. & Bramley, A. N. Static strain aging in high carbon steel wire. Mater. Sci. Tech. 6, 331–337 (1990).
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Wang, F., Qian, D. S., Hua, L. & Lu, X. H. The effect of prior cold rolling on the carbide dissolution, precipitation and dry wear behaviors of M50 bearing steel. Tribol. Int. 132, 253–264 (2019).
The change of free energy (\({\rm{\Delta }}{{G}_{dis}}^{EPT}\)) for the second-phase dissolution process under EPT can be simplified as25:
"We recommend using tooling with internal coolant; this delivers coolant precisely to where it is needed," said Tonne.
Wipers are considered primarily as high-feed-rate machining inserts. Using them shops can increase the feed rate, which translates into less time in the cut, effectively increasing tool life. But if wipers are used at a normal feed rate, shops can gain measurable improvements in surface quality.
Das, A., Ghosh, M., Tarafder, S., Sivaprasad, S. & Chakrabarti, D. Micromechanisms of deformation in dual phase steels at high strain rates. Mater. Sci. Eng. A. 680, 249–258 (2017).
Tonne noted that there is a misconception that shops can use a roughing insert for finishing. Geometries and edge preparations are specifically designed for an application, so he recommends inquiring with the tooling vendor on the best insert, not a universal insert.
Certain applications, particularly critical components in aerospace, have stringent surface integrity requirements. Many shops have had tried-and-true certified processes in place for years. These processes may be working, but with the latest cutting tool advancements, there are often better or more production options available, particularly as they relate to finish turning.
SEM observation of the extracted carbides from the CR specimens (a) without and (b) with EPT, and (c) diameter distribution of extracted carbides.
Bridge, J. E., Maniar, G. N. & Philip, T. V. Carbides in M-50 high speed steel. Metall. Trans. 2, 2209–2214 (1971).
As shown in Fig. 3, the carbides in the CR specimens without and with EPT are extracted and then observed by SEM. It clearly shows that the extracted carbides of the EPT specimen is finer than that of specimen without EPT. According to the analysis of particle size of carbides, the average diameter of carbides decreases from 495 nm to 412 nm after EPT. Furthermore, the particle size distribution of extracted carbides (Fig. 3(c)) indicates that the proportion of carbides with a diameter less than 200 nm is significantly increased after EPT, which therefore coincides with the observation in Fig. 1(b).
Sprecher, A. F., Mannan, S. L. & Conrad, H. Overview no. 49: On the mechanisms for the electroplastic effect in metals, Acta. Metall. 34, 1145–1162 (1986).
Upgrading to newer cutting tools with different coatings or grades can provide significant productivity gains and better surface finishes. Photo courtesy of Sandvik Coromant.
Azuma, M. Structural control of void formation in dual phase steels, PhD thesis, Technical university of Denmark, (2013).
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Liu, X. B. & Zhang, X. F. An ultrafast performance regeneration of aged stainless steel by pulsed electric current. Scr. Mater. 153, 86–89 (2018).
For example, Ti-5553 requires a very hard surface coating to basically get through it. This material can run at only around 50 per cent of the speed of Ti6Al4V.
Lu, Z. C. et al. Effect of electropulsing treatment on microstructure and mechanical properties of intermetallic Al3Ti alloy. J. Alloy. Compd. 708, 834–843 (2017).
Tonne added that titanium is much more sensitive to small changes in speed due to its heat-resistant nature. Speed should only be bumped up in 5-m/min. (15-SFM) steps. It’s also important not to run too slowly, because running below the recommended speed for a given tooling system will cause material to build up on the cutting edge, which effectively dulls the edge.
Having the ability to direct the coolant to the cutting zone is particularly important with titanium. It’s also recommended that shops use both over- and under-coolant for finishing operations and depth of cuts below the nose radius. This allows for the full effect of the high-precision coolant for better chip control, surface finish, and tool life.
In general, the void healing effect induced by EPT can be explained by the inhomogeneous temperature rise caused by the difference of electric resistance between voids and matrix. This inhomogeneous temperature rise can lead to inhomogeneous thermal expansion, so that the voids will be subjected to a strong thermal compressive stress and then consequently healed19. In this work, for the tip region of deformed carbide, the temperature rise around the carbide will be higher because of the detour effect of EPT. As a result, the thermal compressive stress will be greater around the tip region of carbides, which may be more conducive to the healing of the voids around the deformed carbides. Additionally, the dislocation motion around carbides may be another important factor to facilitate the voids healing process. The drift electrons can exert a push on dislocations when high density electric pulses are passing through the CR specimen. Under this force, the rearrangement and annihilation of the dislocations around carbides (Fig. 4(d)) will increase the diffusion velocity of atoms20. Meanwhile, it has been experimentally proved that the voids healing process is controlled by lattice diffusion (transportation of atoms and vacancies)21. Consequently, the generation of thermal compressive stress and acceleration of atoms diffusion will together contribute to the voids healing process of cold rolled M50 bearing steel during EPT.
Kang, M. K. et al. Carbon content of bainite ferrite in 40CrMnSiMoV steel. Mater. Chem. Phys. 118, 438–441 (2009).
The nano-indentation tests are carried out to investigate the hardness of ferrite without and with EPT. As shown in Fig. 5(a), the indentation has been confirmed to be applied on the ferrite matrix and then observed by AFM. The statistical results in Fig. 3(b) show that the average hardness of the ferrite matrix distinctly decreases after EPT regardless of the indenter load, which may be attributed to the recovery of dislocation and occurrence of rapid recrystallization during the EPT (Fig. 4(d))18.
Cabrol, E., Bellot, C., Lamesle, P., Delagnes, D. & Povoden-Karadeniz, E. Experimental investigation and thermodynamic modeling of molybdenum and vanadium-containing carbide hardened iron-based alloys. J. Alloy. Compd. 556, 203–209 (2013).
For many years shops have been using uncoated inserts in titanium, and many still do. But now with so many different types of titanium, there are additional factors to consider for better surface finish when turning.
For finish turning, Burton suggests that polycrystalline diamond (PCD) inserts are the way to go because of the much higher surface speed, which of course reduces cycle time drastically. However, he noted that some shops have a difficult time accepting a visual difference of the surface.
FIB-SEM micrographs collected from the CR specimens (a) without and (b) with EPT. Insert is the EDS analysis of the nano-size particles (marked with blue circle). (c) Distribution of equivalent diameter of voids.
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As a key shape-forming procedure prior to heat treatment, the cold rolling (CR) technology has been proven to have great potential in improving the strength and toughness of low-alloyed bearing steel owing to grain refinement2,3, martensite refinement4, bainite refinement5,6 and solution strengthening7. This raises the speculation that whether the application of CR process will be positive to the comprehensive performance of high-alloyed M50 bearing steel as well. Unfortunately, some results8,9 have shown that the mismatch of strain between the hard phases (cementite or alloy carbides) and soft phases (ferrite) could result in the opening up of voids at the carbides/ferrite interfaces during the CR process with a large plastic deformation, which will deteriorate the final mechanical properties of bearing steel. For the high-alloyed M50 steel with poor formability, the voids are more likely to form during the CR process10. As a result, the industrial application of CR technology in M50 bearing steel has been limited due to the difficulty in preventing or eliminating the nano-size voids.
Li, Z. X., Li, C. S., Ren, J. Y., Li, B. Z. & Zhang, J. Effect of cold deformation on the microstructure and impact toughness during the austenitizing process of 1.0C bearing steel. Mater. Sci. Eng. A. 674, 262–269 (2016).
It’s no secret that titanium alloys are difficult to machine, particularly compared to general and stainless steels. It has poor thermal conductivity and generates high cutting forces and heat at the cutting edge. The demand this material places on cutting tools is significant and can lead to both premature tool wear and poor surface quality if not done properly.
Feng Wang, Dongsheng Qian and Lin Hua conceived and designed the experiments; Feng Wang and Lechun Xie performed the experiments and contributed analysis tools; Huajie Mao and Lechun Xie analysed the data; Feng Wang wrote the paper and made all the figures and tables in this paper.
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Therefore, this study presents the effect of EPT on the nano-size voids induced by the CR process, and then the relevant microstructure evolution was characterized and discussed in detail. It is interesting to find that not only the nano-size voids around carbides have been healed extensively, but also the carbides have been refined by the EPT technology.
The experts agree that shops need to explore many options if they hope to improve surface finish when turning titanium.
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Figure 4(a) shows that high density dislocation is adjacent to a ferrite/carbide interface, which are likely to draw carbon atoms from the carbide due to the higher binding energy of carbon atoms with dislocation27. Once the sink of carbon atoms in the ferrite become supersaturated, partial dissolution of carbides will take place. This phenomenon generally occurs during the process of strain aging28,29. However, when kinetic diffusion of carbon atoms is accelerated by the pulsed electric, the localized carbide dissolution would occur within a short time. Meanwhile, it should be noted that the detour effect30 of electric current results in a higher joule heating adjacent to voids and the tip region of carbide than the overall estimated temperature (532 °C), which will lead the local temperature of carbides to be close to the thermodynamic dissolution temperature. Since the thermodynamic dissolution temperature of Cr-rich carbides is lowest23, the partial dissolution and refinement could be easier to achieve. Conclusively, according to the chemical composition and morphology observation of the refined carbides, it can be inferred that the Cr-rich carbide with a higher surface to volume ratio could be partially dissolved and refined by EPT (especially at the tip region of the deformed Cr-rich carbide).
Lu, X. H., Qian, D. S., Li, W. & Jin, X. J. Enhanced toughness of bearing steel by combining prior cold deformation with martensite pre-quenching and bainite transformation. Mater. Lett. 234, 5–8 (2019).
Song, M., Du, K., Wen, S. P., Nie, Z. R. & Ye, H. Q. In situ electron microscopy investigation of void healing in an Al–Mg–Er alloy at a low temperature. Acta. Mater. 69, 236–245 (2014).
"Titanium in general does not shear efficiently, so the material springs back and the size control of a component is more difficult," said Edwin Tonne, training and technical specialist, Horn USA Inc., Franklin, Tenn. "The finishing pass depth must be carefully maintained to account for this behaviour. Additionally, during finishing the forces and heat are concentrated over a small region of the cutting edge, which breaks down the edge more rapidly than in other materials."
Chakraborty, J., Bhattacharjee, D. & Manna, I. Development of ultrafine bainite + martensite duplex microstructure in SAE 52100 bearing steel by prior cold deformation. Scr. Mater. 61, 604–607 (2009).
Hosoi, A., Nagahama, T. & Ju, Y. Fatigue crack healing by a controlled high density electric current field. Mater. Sci. Eng. A. 533, 38–42 (2012).
In summary, through utilizing the designed EPT processing technology, the extensive voids healing and carbide refinement can be realized within a short time (millisecond level). The generation of thermal compressive stress and acceleration of atoms diffusion will together contribute to voids healing process of cold rolled M50 bearing steel. As well, for the deformed Cr-rich carbide with a higher surface to volume ratio of matrix/carbide, the partial dissolution and refinement of carbides could easily occur due to the decreased thermodynamic dissolution barriers and accelerated kinetic diffusion of carbon atoms towards dislocations during EPT. Moreover, this partial dissolution behavior will result in carbon enrichment in ferrite and accelerate the transformation from ferrite to austenite during subsequent heating.
The voids caused by the cold rolling (CR) quite deteriorates the final performance of M50 bearing steel. In this work, the effect of electropulsing treatment (EPT) on the voids has been investigated, finding that the nano-size voids around carbides have been extensively healed. Moreover, it is interesting to find that the Cr-rich carbides are partially dissolved and consequently refined by EPT, which could be attributed to the decreased thermodynamic dissolution barriers and accelerated kinetic diffusion of carbon atoms towards dislocation. These results inspire people to develop a novel strategy (CR + EPT) to fully take advantage of CR and tailor the carbides size in bearing steels.
"The rule of thumb is the surface finish will be twice as good when a normal feed rate is maintained; doubling the feed rate will maintain normal surface finish," said Burton.
Watté, P., Van. Humbeeck, J., Aernoudt, E. & Lefever, I. Strain ageing in heavily drawn eutectoid steel wires. Scr. Mater. 34, 89–95 (1996).
For observing the effect of EPT on the hardness of ferrite matrix adjacent to carbides, the nano-indentation tests were carried out before and after EPT at peak loads of 1, 2 and 3 mN using a nano-indentation system (NH2, Switzerland). The indentation was applied on the ferrite matrix and confirmed by an atomic force microscope (AFM; DI Nanoscope IV). To investigate the crystal structure information of ferrite, the X-ray diffraction (XRD) data were obtained with a scanning speed of 1°/min on a Rigaku D/MAX-RB diffraction analyser at 12 kW. Furthermore, the differential scanning calorimetry (DSC) experiments were also performed using a PerkinElmer Pyris 1 calorimeter. The specimens for DSC were cut into ϕ 4 mm × 0.5 mm and then heated from ambient temperature to 950 °C at different heating rates of 5, 10, 15, 20 °C/min, respectively.
Ben, D. D. et al. Declined fatigue crack propagation rate of a high‐strength steel by electropulsing treatment. Adv. Eng. Mater. 1801345, 1–8 (2019).
Luminoso has a bachelor of arts from Carleton University, a bachelor of education from Ottawa University, and a graduate certificate in book, magazine, and digital publishing from Centennial College.
A wiper insert is built up through a number of extra radii. This makes the engagement surface longer, which also affects the surface in a positive way. A long engagement surface also affects the cutting force and the vibration sensitivity.
Kresse, T. et al. Influence of supersaturated carbon on the diffusion of Ni in ferrite determined by atom probe tomography. Scr. Mater. 69, 424–427 (2013).
Figure 4 shows the TEM observation of the microstructure for the CR specimens without and with EPT. For the CR specimens without EPT, the void adjacent to carbide can be found as shown in Fig. 4(a). The HRTEM observation in Fig. 4(b,c) indicates that high dislocation tangle has entangled in the ferrite matrix around carbides for the CR specimens. This result may lie in the fact that the carbides could act as the strong obstacles to inhibit dislocation motion during the CR process. However, the significant recovery of entangled dislocations occurs within a short time of EPT (Fig. 4(d)), which could be attributed to the increased mobility of dislocation by the effect of electron wind force17. In addition, it is also showed that fine recrystallization grains formed around the carbide, indicating the occurrence of rapid recrystallization during the EPT.
Finish turning of titanium must be a wet process. A high-precision coolant offers significant advantages, particularly as it can be directed to the cutting zone.
Ma, Y. R., Yang, H. J., Tian, Y. Z., Pang, J. C. & Zhang, Z. F. Hardening and softening mechanisms in a nano-lamellar austenitic steel induced by electropulsing treatment. Mater. Sci. Eng. A. 713, 145–150 (2018).
"When we start finish-turning with PCD, it looks totally different than with other inserts," said Burton. "The titanium will look really nicely polished and almost have a hardened steel, superfinished look."
"All titanium runs with the same general parameters is one misconception," said Tonne. "Usually the phase of the metallurgy is the best starting point. Alpha phase titanium alloys tend to run higher speeds and feeds. Alpha beta, which is the most prevalent, is well-documented, and finally beta alloys are the most difficult. The key is to research the material and understand the properties."
Easily access valuable industry resources now with full access to the digital edition of Canadian Metalworking.
The experts recommend using a physical vapour deposition- (PVD-) coated insert because it is thinner. With titanium, it’s not advisable to use a thick coating because of the chemical reaction that can occur. Many of today’s coatings have titanium in them, like TiCN, which is used in chemical vapour deposition (CVD). This is why PVD is more commonly recommended.
Burton noted that although current processes may be working, upgrading to newer cutting tools with different coatings or grades can provide significant productivity gains and better surface finishes.
(a) The XRD patterns of the CR specimens without and with EPT; the DSC curves of the CR samples (b) without and (c) with EPT at different heating rates; (d) The volume fraction of austenite formed as a function of temperature at 5 °C/min.
The novel phenomenon provides a new pathway for fully eliminating the deteriorating effect of voids on mechanical properties and maximizing the advantages of CR in bearing steel. Meanwhile, it is of great engineering significance to tailor the carbides size in bearing steels using the efficient and energy-saving EPT processing technology, in the context of cold rolled bearing steel.
Yu, T., Deng, D. W., Wang, G. & Zhang, H. C. Crack healing in SUS304 stainless steel by electropulsing treatment. J. Clean. Prod. 113, 989–994 (2016).
Wang, F., Qian, D., Hua, L. et al. Voids healing and carbide refinement of cold rolled M50 bearing steel by electropulsing treatment. Sci Rep 9, 11315 (2019). https://doi.org/10.1038/s41598-019-47919-6
In order to further verify the partial dissolution behavior of carbides, the XRD patterns for the CR specimens with and without EPT are obtained, as shown in Fig. 6(a). According to the Gaussian fitted curves of (110)α diffraction peak (as insert in Fig. 6(a)), the values of FWHM can be measured (Table 2) and shows a distinct decrease after EPT, which therefore verifies the dislocation recovery as observed in Fig. 4. Moreover, it can be clearly seen that the ferrite diffraction peak shifts to smaller angle after EPT. This indicates that the lattice parameter of α-Fe increases after EPT. The carbon content in the ferrite can be estimated based on the relationship between the lattice parameter and carbon constant of α-Fe given by Fasiska and Wagenblast31 as follow: \({a}_{\alpha }(nm)=(0.28664\pm 0.0001)\,\)\(+\,(0.84\pm 0.08)\times {10}^{-3}\cdot {[C]}_{\alpha }\). where aα is the lattice parameter of α-Fe, and [C]α is the carbon content in α-Fe (at.%). Based on the measured lattice parameters, the carbon content in α-Fe before and after EPT is calculated and listed in Table 2, where it can be seen that the carbon content in α-Fe increases substantially after EPT. Obviously, compared to the carbon content in equilibrium ferrite (the solid solubility of carbon in ferrite at 727 °C is 0.0218 wt.%32), the determined carbon content in ferrite after EPT is supersaturated. This result clearly confirms the migration of carbon from carbides to ferrite and partial dissolution of carbides during EPT.
To further verify the occurrence of voids healing, the quasi in-situ observation of the void is performed as shown in Fig. 2. The initial void with long axis of about 260 nm locates between two strip carbides, which may be caused by the movement of carbide fragments during plastic deformation16. After EPT, the diameter of void decreases to about 80 nm, thereby validating the contribution of EPT to the healing of the voids around carbides. It is also found that the tip region of deformed carbide has been partially disappeared after EPT as circled in Fig. 2(b), which may result from the localized dissolution of carbides. Furthermore, the EDS results of point A and B are shown in Fig. 2(c,d). It can be seen that there is larger amount of Mo element existing in the broken strip carbide (marked with A), whereas the partially dissolved carbide is rich in Cr element (marked with B). The results, together with the chemical analysis in Fig. 1, prove that the Cr-rich carbides have lower stability under EPT.
Furthermore, the carbon-supersaturated ferrite results in a decrease of the carbon chemical potential between the ferrite and carbides, which will facilitate the transformation of ferrite to austenite33. Figure 6 (b,c) illustrates the DSC curves of the CR samples without and with EPT at different heating rates. Obviously, the peak transformation temperature of α → γ increases with the increase of heating rate. Based on the Kissinger method34, the activation energy for the transformation from ferrite to austenite (Qα→γ) is obtained in Table 2, which indicates a distinct decrease of Qα→γ after EPT. Meanwhile, the volume fraction of austenite formed as a function of temperature at 5 °C/min is plotted in Fig. 6(d), which demonstrates that the transformation of α → γ shifts to lower temperature. Therefore, the EPT not only leads to partial dissolution of carbides but also accelerates the transformation from ferrite to austenite during subsequent heating by increasing the carbon solid-solute in ferrite.
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Sauvage, X., Copreaux, J., Danoix, F. & Blavette, D. Atomic-scale observation and modelling of cementite dissolution in heavily deformed pearlitic steels. Philos. Mag. A. 80, 781–796 (2000).
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TEM observation of the microstructure from the CR specimens (a) without and (d) with EPT, (b,c) HRTEM observation of the dislocation tangle around carbide in the CR specimens.
M50 bearing steel used in this study with the nominal composition is presented in Table 1. The material was received as spheroidize-annealed bar and an initial microstructure of primary carbides in ferritic matrix. The ring blank used for CR was prepared with the dimension (outer diameter: 54.5 mm; inner diameter: 34.5 mm) and then cold rolled for a total thickness reduction of 50% using a radial ring rolling machine. After the CR tests, the EPT specimens with a size of 16 × 8 × 4 mm were obtained from the CR ring using wire-electrode cutting. The EPT experiments were conducted by a self-made electropulse generator under ambient conditions. The pulsed electric current was applied for a total duration of 160 ms and had a peak current density of 10.7 kA/cm2 with a frequency of 50 Hz. During the EPT, the maximum temperature rising of the specimens caused by joule heating was measured to be 532.0 °C by means of an infrared camera (Fotric 226).