Reloading for the Glock G40 - carbide insert for brass

Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central University for Nationalities, Wuhan, 430074, China

a XRD diffraction patterns for θ-Fe3C@graphene sample (black line), θ-Fe3C@graphene sample reduction under flowing H2 at 623 K for 3 h (red line), and then carbonization under flowing syngas (H2/CO = 1) at 573 K for 10 h (blue line). b 57Fe Mössbauer spectra for θ-Fe3C@graphene, ε-Fe2C@graphene-C, and ε-Fe2C@graphene-S samples. Representative high-resolution TEM micrographs for c θ-Fe3C@graphene and d ε-Fe2C@graphene-C. Scale bar, 2 nm.

The θ-Fe3C@graphene samples obtained above were reduced in a flow of 3 L gcat−1 h−1 of H2 at 623 K for 3 h (denoted as Fe@graphene), and then the carbonization in a flow of 64 L gcat−1 h−1 of syngas (H2/CO = 1) at 573 K for 10~400 h (denoted as ε-Fe2C@graphene).

Peer review information Nature Communications thanks the anonymous reviewers for their contribution to the peer review of this work.

Xu, J. & Bartholomew, C. R. Temperature-programmed hydrogenation (TPH) and in situ Mössbauer spectroscopy studies of carbonaceous species on silica-supported iron Fischer-Tropsch catalysts. J. Phys. Chem. B 109, 2392–2403 (2005).

Hong, S. Y. et al. A new synthesis of carbon encapsulated Fe5C2 nanoparticles for high-temperature Fischer-Tropsch synthesis. Nanoscale 7, 16616–16620 (2015).

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Yu, G. et al. FexOy@C spheres as an excellent catalyst for Fischer-Tropsch synthesis. J. Am. Chem. Soc. 132, 935–937 (2009).

The iron carbide nanocomposites were synthesized by pyrolysis of a molten mixture of urea, glucose, and Fe(NO3)3•9H2O. In a typical synthesis, an amount of Fe(NO3)3•9H2O, corresponding to the final Fe loading of 30–60 wt%, was mixed with 5.0 g urea and 3.0 g glucose at 393–433 K to form a transparent solution. The resultant molten mixture was heated at 453 K in an oven for 24 h. The solid collected was subjected to a heat treatment in flowing N2 (10 mL min−1) at 673 K for 30 min and finally at the final temperatures (773–1023 K) for another 2 h.

a Comparison of FTY values between ε-Fe2C@graphene catalyst and iron catalyst loaded on active carbon with different iron loadings. b Long-term stability of ε-Fe2C@graphene and un-encapsulated χ-Fe5C2 catalysts. Reaction conditions: H2/CO = 1/1, 573 K, p = 10 bar. The insert shows the high-resolution TEM micrograph for the spent ε-Fe2C@graphene catalysts after 400 h reaction. Scale bar, 5 nm.

The CO chemisorption was performed using a Micromeritics AutoChem II 2920 unit. Before CO chemisorption, 0.1 g of catalyst was reduced under flowing pure hydrogen at 623 K for 3 h and then carburized in syngas (H2/CO = 1) at 573 K for 5 h. Subsequently, the adsorbed species were removed by flowing He at 823 K for 2 h. The samples were cooled to 308 K, then CO chemisorption experiment was conducted. The average CO:Fe stoichiometry was assumed 1:2. For θ-Fe3C@graphene catalyst, reduction and carburization processes are eliminated.

a Relative chemical potential of carbon (ΔμC) for carburization by CO (2CO → C + CO2). b Relative chemical potential of carbon (ΔμC) for carburization by syngas (4CO + 4H2 → 2C + CO2 + 2H2O + CH4). c Surface-normalized carbon absorption energy (ωabs) of ε-Fe2C surfaces with and without graphene(-N) layers and the most stable structures labeled by the distances between ε-Fe2C and graphene (data in parenthesis referring to those of graphene-N).

We acknowledge Dr. Kenneth G. Rappé (Pacific Northwest National Laboratory), Prof. Norbert Kruse (Washington State University), Prof. Zhao-Xu Chen (Nanjing University), and Prof. Jianyu Huang (Yanshan University) for helpful discussions. This work was supported by the National Natural Science Foundation of China (22072184, 21972170), the Joint Fund of National Natural Science Foundation of China (U1463210).

“More recently the company has set up a production facility in India and expanded its production and R&D facilities in Korea where it is regarded as the number one cutting tool manufacturer in that country and now among the top five in the world.”

Lee, H. K. et al. Extremely productive iron-carbide nanoparticles on graphene flakes for CO hydrogenation reactions under harsh conditions. J. Catal. 378, 289–297 (2019).

The development of efficient catalysts for Fischer–Tropsch (FT) synthesis, a core reaction in the utilization of non-petroleum carbon resources to supply energy and chemicals, has attracted much recent attention. ε-Iron carbide (ε-Fe2C) was proposed as the most active iron phase for FT synthesis, but this phase is generally unstable under realistic FT reaction conditions (> 523 K). Here, we succeed in stabilizing pure-phase ε-Fe2C nanocrystals by confining them into graphene layers and obtain an iron-time yield of 1258 μmolCO gFe−1s−1 under realistic FT synthesis conditions, one order of magnitude higher than that of the conventional carbon-supported Fe catalyst. The ε-Fe2C@graphene catalyst is stable at least for 400 h under high-temperature conditions. Density functional theory (DFT) calculations reveal the feasible formation of ε-Fe2C by carburization of α-Fe precursor through interfacial interactions of ε-Fe2C@graphene. This work provides a promising strategy to design highly active and stable Fe-based FT catalysts.

L.W. and J.L. supervised the whole project and designed the study. L.W., J.L., and Y.W. co-wrote the manuscript. S. L., S.Y., and J.C. performed most of the experiments and analyzed the experimental data. Z.L. helped to do the DFT simulations. Y.Z. performed reaction testing. All the authors discussed the results and assisted during the manuscript preparation.

a Conventional catalysts with unconfined iron carbide (FexC) particles as the active phase. b Graphene layer-confined ε-Fe2C.

Here, the thermal stability ε-Fe2C@graphene enables us to investigate its catalytic performance at 573 K. The FTY value of ε-Fe2C@graphene at 573 K was 582.8 μmolCO gFe−1 s−1 (Table 1), which was significantly higher than those for the un-encapsulated χ-Fe5C2 derived from Fe2O3 and the θ-Fe3C@graphene catalysts. The intrinsic activity (TOF values) of ε-Fe2C is ~6–10 times higher than the θ-Fe3C and 2 times higher than the χ-Fe5C2. Furthermore, CO-TPD profiles of ε-Fe2C@graphene catalyst show a multi-peak overlapped cure with a maximum peak position at ca. 843 K, which is attributed to desorption of CO after recombination of dissociated carbon and oxygen on the surface (Supplementary Fig. 7). The result revealed the strongly bound CO on the surface due to the confinement effect of ε-Fe2C@graphene catalyst. In addition, the CO2 selectivity for the ε-Fe2C@graphene catalyst was lower than those for the other two reference catalysts, indicating that the ε-Fe2C is a more active and selective phase for the conversion of syngas to hydrocarbons.

Xiong, H. et al. Fischer-Tropsch synthesis: Iron catalysts supported on N-doped carbon spheres prepared by chemical vapor deposition and hydrothermal approaches. J. Catal. 311, 80–87 (2014).

Xu, J., Yang, Y. & Li, Y. Fischer-Tropsch synthesis process development: steps from fundamentals to industrial processes. Curr. Opin. Chem. Eng. 2, 354–363 (2013).

For comparison, we further studied the changes in structures of θ-Fe3C@graphene samples before and after treatment under different conditions (Supplementary Fig. 4). The direct carburization of θ-Fe3C@graphene did not induce any detectable change in the phase composition, probably because this sample was formed by a prior carburization process. Fe2O3 was obtained by oxidation of θ-Fe3C@graphene and served as a carbon encapsulation-free reference. The carburization treatment of Fe2O3 led to the formation of Fe3O4 and χ-Fe5C2. The characterization result shows that only χ-Fe5C2 could be observed at 573 K, which is the thermodynamic stable phase at high temperatures. On the other hand, the carbon-encapsulated metal Fe sample only formed the ε-Fe2C phase after the carburization treatment. The ε-Fe2C phase can be stabilized by the graphene layer even at such a high temperature.

Cheng, K. et al. Advances in catalysis for syngas conversion to hydrocarbons. Adv. Catal. 60, 125–208 (2017).

Raman spectroscopy was used to identify the nature of the graphene layers. Two bands at 1350 and 1590 cm−1 were observed in the Raman spectra for ε-Fe2C@graphene-C and ε-Fe2C@graphene-S, corresponding to the D-band (disordered carbon) and the G-band (graphene carbon), respectively (Supplementary Fig. 5). A lower ID/IG intensity ratio for the ε-Fe2C@graphene was observed, consistent with a higher degree of graphene of the carbon matrix35. The 2D bands of the two ε-Fe2C@graphene samples are closely related to the band structure of graphene layers36. These observations suggest that while the iron phase undergoes changes under different atmospheres, the graphene layers keep surrounding the particle of iron or iron carbide.

Wang, P. et al. Synthesis of stable and low-CO2 selective ε-iron carbide Fischer-Tropsch catalysts. Sci. Adv. 4, eaau2947 (2018).

“We are so confident of the local market that we are investigating the possibility of opening a local manufacturing plant. For some time we have wanted to have a permanent presence in South Africa but only now has the opportunity arisen,” concluded H K Song.

“We are targeting to equip as many machines as possible with our vast range of products covering HSS, milling, drilling, turning, threading as well as boring. The YG-1 company was established in 1982 and has been growing as a leading global manufacturer in the cutting tool industry. YG-1 operates its global business through nine overseas production sites including the United States, Ireland, South Korea and China, has 30 sales subsidiaries and has a presence in 75 countries.”

“The products find applications across industries, such as aerospace, die and mould, automobile, oil and gas, power, electronics, general engineering and medical equipment. We will be holding a sizeable amount of products and stock to cover all these fields of metal cutting. In fact clients will now be exposed to a greater array of YG-1 products, which they were not in the past.”

Chen, X., Deng, D., Pan, X., Hu, Y. & Bao, X. N-doped graphene as an electron donor of iron catalysts for CO hydrogenation to light olefins. Chem. Commun. 51, 217–220 (2015).

For CO temperature-programmed desorption (CO-TPD), 0.1 g of catalyst was reduced under flowing pure hydrogen at 623 K for 3 h and then carburized in syngas (H2/CO = 1) at 573 K for 5 h. Subsequently, the adsorbed species were removed by flowing He at 573 K for 2 h. The samples were cooled to 308 K. At this temperature, the carburized sample was flushed with CO for 1 h and consequently purged with He until the baseline of CO signal leveled off. Finally, the sample was heated to 1,073 K at a ramp of 10 K min−1. For θ-Fe3C@graphene catalyst, reduction and carburization processes are eliminated.

Kang, S. et al. High-performance Fe5C2@CMK-3 nanocatalyst for selective and high-yield production of gasoline-range hydrocarbons. J. Catal. 349, 66–74 (2017).

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Xu, K. et al. ε-Iron carbide as a low-temperature Fischer-Tropsch synthesis catalyst. Nat. Commun. 5, 5783–5783 (2014).

57Fe Mössbauer spectroscopy of ε-Fe2C@graphene-C provided further evidence for the formation of ε-Fe2C after the carburization (Fig. 2b and Supplementary Table 1). Moreover, after 100 h reaction in syngas at 573 K (denoted as ε-Fe2C@graphene-S), the ε-Fe2C content remained constant (about 62.8%), indicating the stabilizing effect by the graphic carbon layer on ε-Fe2C even under reaction conditions (Fig. 2b and Supplementary Table 1).

“This is just the beginning of a journey. YG-1 has an established name in South Africa and we intend to grow that reputation and increase our market share in HSS tooling and carbide cutting tools. The local metal working industry will now be able to benefit from having a dedicated team that will only concentrate on supplying YG-1 products to a broad spectrum of engineering companies,” said Hockly who set up the company in October 2017.

de Smit, E. et al. Stability and reactivity of ε-χ-θ iron carbide catalyst phases in Fischer-Tropsch synthesis: controlling μc. J. Am. Chem. Soc. 132, 14928–14941 (2010).

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Lyu, S. et al. Role of active phase in Fischer-Tropsch synthesis: experimental evidence of CO activation over single-phase cobalt catalysts. ACS Catal. 8, 7787–7798 (2018).

Our confined iron carbide catalyst was synthesized by a pyrolysis method, followed by reduction with H2 and carburization in syngas flow. X-ray diffraction (XRD) measurements and 57Fe Mössbauer spectroscopy showed that θ-Fe3C was the major Fe phase in the precursor obtained after pyrolysis (Fig. 2a, b). Transmission electron microscopy (TEM) results clarified that most of the iron carbide nanoparticles were well dispersed with a near-spherical morphology and had a mean size of 13.6 nm (Supplementary Fig. 1a). The high-resolution TEM (HRTEM) studies revealed that the θ-Fe3C nanoparticles were surrounded and closely attached by graphene layers (Fig. 2c and Supplementary Fig. 1b). The lattice fringes with d spacing values of 0.30 and 0.34 nm, which corresponded to the (111) facet of θ-Fe3C and the (002) facet of graphene, respectively, were observed (the insert of Supplementary Fig. 1b). These results indicate that the precursor obtained after pyrolysis is in the structure of θ-Fe3C@graphene.

State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

“Machining is now becoming increasingly advanced with machine tool builders manufacturing more sophisticated machines with higher speeds and accuracy. We as YG-1 have to keep up with the technological advancement in the metal cutting field. To this end YG-1 has two R&D centres operating in South Korea, one in Songdo and another in Chungju.”

In summary, we synthesized graphene layers encapsulated ε-Fe2C nanocrystals for the FT reaction. It exhibited remarkably activity (~ 1258 μmolCO gFe−1 s−1) and stability (>400 h) under realistic FT synthesis conditions. The confinement effects of graphene layers stabilize the metastable but very active ε-Fe2C phase. The unique confinement structure (ε-Fe2C@graphene) can inhibit the formation of an amorphous carbon layer that converts catalytically active ε-Fe2C phase to other less active carbide phases (e.g., χ-Fe5C2). Our results and conclusion could help in the rational design of promising active phases in industrial catalysts for hydrogenation processes.

In addition, taking (1-21) as an example, we further investigate the mechanism of CO dissociation on the ε-Fe2C surface with and without graphene confinement. Both the direct and H-assisted dissociations are considered including different active sites of perfect ε-Fe2C, graphene, and the C-vacancy on ε-Fe2C (Supplementary Figs. 11–15). The C-vacancy on ε-Fe2C is more active for the direct CO dissociation with a lower energy barrier (Ea) of ca. 1.2 eV than those of direct and H-assisted dissociations (2.57-2.61 and 2.83-2.87 eV) on the perfect ε-Fe2C surface with and without the confinement of graphene. The CO dissociation on the graphene site hardly occurs due to the high Ea values (> 2.89 eV). Similar results can be found for graphene-N. The confinement of graphene or graphene(-N) favors to improve the stability of the highly active ε-Fe2C to achieve the high catalytic performance of FT at high temperature.

de Smit, E. & Weckhuysen, B. M. The renaissance of iron-based Fischer-Tropsch synthesis: on the multifaceted catalyst deactivation behaviour. Chem. Soc. Rev. 37, 2758–2781 (2008).

Huang, F. et al. Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation of acetylene. Nat. Commun. 10, 1–7 (2019).

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On the other hand, the confinement effects are modeled by covering the ε-Fe2C surfaces with a single graphene layer. The optimized distance between ε-Fe2C and graphene is ca. 3.9–4.3 Å (Fig. 5c) close to the dynamic diameter of reactants and single-chain hydrocarbons42,43, which can afford the catalytic FT reaction on the ε-Fe2C surfaces with the graphene confinements. The ωabs values for the graphene-covered ε-Fe2C are lower than those of the pristine ε-Fe2C surfaces, indicating the improved thermodynamic stability. The N-doped graphene (graphene-N) show similar results to those of graphene.

In addition, the surface composition of the graphene layers is of particular interest and surface contents of N, O, and Fe were determined by X-ray photoelectron spectroscopy (XPS). The θ-Fe3C@graphene sample has a surface atomic ration of Fe/C of about 0.03, and the surface contents of N, O, and Fe elements did not vary with an increase of the Fe loading in the catalysts (Supplementary Table 2). The results revealed a negligible surface iron content, suggesting that θ-Fe3C nanoparticles were encapsulated by the graphene layers in the catalysts.

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Thermogravimetric analysis (TGA) was carried out on a NETZSCH TG 209F3 TGA analyzer during temperature ramping from 303 K to 1,173 K in flowing air (50 mL min−1) with a ramping rate of 10 K min−1.

The data that support the plots within this paper and other findings of this study are available from the corresponding author upon request.

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Here, we develop a surface-normalized carbon absorption energy (ωabs), which is suitable for describing the surface carburization of iron carbide with and without graphene confinement. The most abundant (101), (1-21), and (2-21) surfaces were selected to evaluate the confinement effects of graphene layers on the ωabs (Fig. 5c). The negative ωabs values indicate the favorable stability of the ε-Fe2C surfaces under the conditions of pretreatment and FT reaction. Although the surface stability follows the order of (101) > (1-21) > (2-21) according to the calculated surface energy (Supplementary Table 4), the (1-21) has the highest carburization feasibility from metallic iron because of the lowest ωabs value.

Khodakov, A. Y., Chu, W. & Fongarland, P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. Chem. Rev. 107, 1692–1744 (2007).

Range of inserts “Although the company is very strong in tapping, drilling and threading, what is not commonly known in South Africa is that YG-1 manufacture and supply a vast range of turning and milling inserts. The company has spent over $US 100 million in this area of development over the last five years and recently inaugurated another dedicated plant in Chungju, Korea to manufacture carbide inserts, including end mills.”

X-ray diffraction (XRD) patterns of the samples were recorded on a Bruker D8 powder diffractometer equipped with a Cu-Kα source operated at 40 kV and 40 mA and a Vantec-1 detector.

a θ-Fe3C@graphene samples reduction under flowing H2 at 623 K for 3 h, and then treated under syngas (H2/CO = 1) at different temperature. b θ-Fe3C@graphene samples reduction under flowing H2 at 623 K for 3 h, and then treated under different CO pressure at 573 K.

XPS characterizations were further performed to analyze carbon and nitrogen bonding configurations in the carburization process of Fe@graphene. N 1s peaks in XPS of θ-Fe3C@graphene (Supplementary Fig. 6a, b) can be fitted into four peaks at 398.3 eV, 399.6 eV, 400.8 eV, and 402.5 eV referring to the pyridinic, pyrrolic, graphitic and oxidized nitrogen, respectively37. These results confirmed the existence of N functional groups (pyridinic-N, pyrrolic-N, and graphitic-N), indicating unique defect-rich structure graphene layers after the annealing process. Moreover, the XPS results clearly confirmed the presence of defective graphene layers during the reducing and carburization processes (Supplementary Fig. 6c, e) and the incorporation of nitrogen atoms within the graphene layers (Supplementary Fig. 6d, f). From the above Raman spectra, STEM/HRTEM images, and XPS results, we conclude that the highly defective graphene layers have been successfully synthesized during the thermal annealing. The number of defects and type of doped N in carbons might play a crucial role in enhancing FT reaction catalytic performance38,39. N 1s XPS spectra of the few graphene layers confined iron catalysts reveals that the graphitic N is the most abundant N species, indicating that the graphitic N could affect the performance of confined iron catalysts, which is rationalized by our theoretical modeling shown in the part of DFT calculation.

Santos, V. P. et al. Metal organic framework-mediated synthesis of highly active and stable Fischer-Tropsch catalysts. Nat. Commun. 6, 6451–6458 (2015).

Fischer–Tropsch (FT) synthesis transforms syngas (a mixture of CO and H2) into multi-carbon hydrocarbons, which can be liquid fuels and chemicals. Because FT synthesis is a core reaction in the utilization of various non-petroleum carbon sources (such as coal, natural or shale gas, biomass, and CO2) to supply energy and chemicals, the development of efficient FT catalysts has received much-renewed interest in recent years1,2,3,4,5,6. Iron-based catalysts have widely been used in the industrial FT process because of the low cost of iron, wide operation conditions, and flexible product distributions7. However, Fe-based catalysts usually suffer from low activity and stability3, and thus many recent fundamental studies have been devoted to enhancing the FT activity and stability of Fe catalysts by employing different modifiers or different supports8,9,10,11,12,13,14. Unlike Ru- or Co-based FT catalysts, where metallic Ru0 or Co0 functions as the active phase, metallic Fe0 is unstable and the evolution of a conventional Fe-based catalyst typically results in a mixture of different iron phases including Fe3O4 and iron carbides under FT reaction conditions15,16,17,18,19,20,21. Iron carbides are believed to be responsible for the activation of CO and the chain growth in FT synthesis, but the nature of the true active iron-carbide phase is still under debate and this hinders the rational design of highly active and stable Fe-based FT catalysts.

Cheng, J. et al. Density functional theory study of iron and cobalt carbides for Fischer-Tropsch synthesis. J. Phys. Chem. C. 114, 1085–1093 (2010). M.

Hägg χ-Fe5C2 has been observed in many Fe-based catalysts after FT reactions or during in situ characterizations22,23,24. These observations form the current consensus that χ-Fe5C2 is the active phase for FT synthesis. The pure-phase χ-Fe5C2 was also successfully synthesized and was confirmed to be efficient for FT synthesis25,26. Theoretical calculations also predicted that χ-Fe5C2 surfaces catalyzed the CO activation and C-C chain growth27,28, and χ-Fe5C2 should be more active than metallic Fe27. Nevertheless, a recent work disclosed that the octahedral carbide ε-Fe2C, which contains carbon atoms in octahedral interstices of hexagonal closed-packed iron lattice, was more active than a χ-Fe5C2-dominant catalyst in the low-temperature (≤473 K) FT reaction29. The Fe catalyst based on ε-Fe2C phase could also decrease the CO2 selectivity during FT synthesis30. However, it is known that ε-Fe2C would be transformed into χ-Fe5C2 at above 523 K, and thus would be unstable at a higher temperature (~573 K) that is usually adopted for Fe-catalyzed FT synthesis. Under FT reaction, Fe-based catalysts are usually coated with an amorphous carbon/carbide layer that facilely induces the carbides transformation (Fig. 1a)31,32. Thus, it is highly challenging to synthesize stable catalysts that are dominated by the highly active ε-Fe2C phase for FT synthesis.

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For graphene layers covered metal catalysts, it was demonstrated that defects on graphene layers render the channels for the diffusion of active species through the grain boundaries on the metal surface33. Molecules such as CO, H2, and H2O can go through domain boundaries and point defects (such as pentagon-heptagon defects and vacancies) on the 2D material overlayers, which mainly follow the defect-aided intercalation mechanism34. In addition, the Raman spectra of ε-Fe2C@graphene catalyst show that the 2D peak position of ε-Fe2C@graphene blueshifted relative to single-layer graphene and the peak pattern consistent to the few graphene layers rather than bulk graphite (Supplementary Fig. 3).

After the reduction by H2 at 623 K, α-Fe became the major iron phase, indicating that θ-Fe3C was decomposed into Fe (Fig. 2a). This was also confirmed from HRTEM images, showing that the nanoparticle of α-Fe remains encapsulated by graphene layers after the reduction. The carburization of α-Fe@graphene under syngas at 573 K transformed α-Fe into iron carbide again (denoted as ε-Fe2C@graphene-C). It is of interest that ε-iron carbide (ε-Fe2C) rather than θ-Fe3C or χ-Fe5C2 was formed after the carburization (Fig. 2a). The HRTEM result reveals that the ε-iron carbide is surrounded by the graphene layers (Fig. 2d). It can be clearly seen by spherical aberration-corrected scanning transmission electron microscopes (Cs-corrected STEM) that the graphene layers of ε-Fe2C@graphene catalyst are about 2–7 layers and a large number of defects spread over carbon layer outside ε-Fe2C@graphene catalyst (Supplementary Fig. 2).

Jin, Y. & Datye, A. K. Phase transformations in iron Fischer-Tropsch catalysts during temperature-programmed reduction. J. Catal. 196, 8–17 (2000).

An, B., Cheng, K., Wang, C., Wang, Y. & Lin, W. Pyrolysis of metal-organic frameworks to Fe3O4@Fe5C2 core-shell nanoparticles for Fischer-Tropsch synthesis. ACS Catal. 6, 3610–3618 (2016).

The size and morphology of samples were determined using a FEI Tecnai G20 transmission electron microscope operated at 200 kV and a Hitachi SU8000 field emission scanning electron microscope at an accelerating voltage of 15 kV.

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To gain further insights into the possible evolution of iron phases, we have performed in situ XRD characterizations for our sample in syngas flow under different conditions. α-Fe was still the major phase under syngas with a H2/CO ratio of 1 at 473 K and was gradually changed to ε-Fe2C phase upon increasing the temperature from 473 to 573 K (Fig. 3a). In addition, during the carburization process, ε-Fe2C phase kept stable in syngas flow at 573 K for 5 h and remained almost unchanged by changing the CO pressure at 573 K (Fig. 3b). It is noteworthy that conventionally ε-Fe2C is unstable and would be converted to χ-Fe5C2 and θ-Fe3C at ≥ 523 K20. Interestingly, we observed the formation of ε-Fe2C phase in a wide range of temperature and CO pressure, which are closely related to the model of carbon chemical potential (μC) as explained in the computational details of Supplementary Methods. Thus, the present results clearly demonstrate that the confinement of ε-Fe2C inside graphene layers can keep it from phase transformations probably.

Fischer–Tropsch synthesis was performed in a stainless steel fixed-bed reactor (i.d. = 12 mm). Catalysts were diluted with inert SiC particles in a mass ratio of 1:10 prior to testing. The diluted catalysts (5.5 g) were pre-treated in flowing H2 (10 mL min−1) at 623 K for 3 h before reactions. The pre-treated catalysts were cooled to 373 K in flowing H2 before the introduction of syngas (H2/CO = 1). The reaction temperature was then ramped slowly to 593 K. The permanent gases (H2, CO, CO2) and light alkanes (CH4, C2H6, etc.) in the effluent of the reactor were monitored by an online Agilent Micro GC3000A gas chromatograph (GC) equipped with the molecular sieve, Plot-Q and Al2O3 capillary columns and a TCD detector. The oil and wax products were separated using a cold trap (271 K) and a hot trap (423 K), respectively, while the aqueous products were obtained by phase separation in those traps. The oil products were analyzed using an Agilent 6890N GC with a FID detector and a HP-5 column; the wax products were dissolved in CS2 and analyzed using an Agilent 7890A GC equipped with a FID detector and a HT5 column; the aqueous fraction was analyzed using an Agilent 4890 GC equipped with a FID detector and a HP-Innowax column. The product selectivity was calculated based on the carbon balance.

YG-1, whose cutting tools have been widely distributed in South Africa for many years, has decided to open up a subsidiary in South Africa. The South African subsidiary company – YG-1 South Africa Pty Ltd – is based in the Brentwood Park, Benoni area of Gauteng and is headed up by Lance Hockly, who has been in the cutting tool industry for a number of years.

Density functional theory calculations were performed using the generalized gradient approximation Perdew–Burke– Ernzerhof of (PBE) functional44 and projector-augmented wave (PAW) method45 as implemented in the Vienna ab initio simulation package (VASP)46. A second-order Methfessel–Paxton electron smearing scheme (sigma = 0.2 eV) was used because of the metallic conductor properties of iron carbide. Plane-wave kinetic energy cut off of 400 eV is sufficiently accurate for the spin polarization calculations of the electronic properties of open-shell iron carbide. Energy and force convergence criteria were 10−5 eV and 0.03 eV Å−1, respectively. The most abundant ε-Fe2C(1-21), ε-Fe2C(101), and ε-Fe2C(2-21) surfaces were taken into account. A vacuum of 15 Å was used for screening the interactions vertical to the surface. The most stable configurations were selected to model the confinement effects of graphene and N-doped graphene (graphene-N) on the carburization feasibility of ε-Fe2C from metallic iron and the reaction mechanism of CO dissociation. The computational details are deposited in Supplementary Methods.

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The 57Fe Mössbauer measurements were performed at room temperature or 77 K using a conventional spectrometer (Germany, Wissel MS-500) in transmission geometry with constant acceleration mode. A 57 Co(Rh) source with an activity of 25 mCi was used. The velocity calibration was done with a room temperature α-Fe absorber. The spectra were fitted by the software Recoil using Lorentzian Multiplet Analysis. The samples were passivated in flowing 1% O2/N2 for 1 h at room temperature prior to air exposure and being sealed in a sample holder with paraffin wax for Mössbauer spectroscopy measurements.

Here, we attempt to replace the amorphous carbon with few graphene layers that confines the Fe-based catalyst. The confinement of the rigid geometry of the graphene shell can inhibit the formation of the amorphous carbon layer and improve the stability of highly active ε-Fe2C (Fig. 1b). We report our finding that the confinement of ε-Fe2C inside graphene layers (denoted as ε-Fe2C@graphene) can stabilize this metastable phase for FT synthesis at 523–613 K. The Fe-time yield (FTY), which is defined as the moles of CO converted to hydrocarbons per gram of Fe per second, reaches 1258 μmolCO gFe−1 s−1 at 613 K, breaking the upper-limit value (1000 μmolCO gFe−1 s−1) reported for Fe-based FT catalysts12,13. The catalyst is highly stable under our FT reaction conditions and high CO conversion (~ 95%) can be kept at 573 K at least for 400 h. DFT calculations suggest that the confinement effects of graphene layers favor the formation of ε-Fe2C from carburization of α-Fe, which maintains the high stability of ε-Fe2C under high-temperature FT reaction conditions. On the other hand, the facile transformation of FexC particles may occur during FT synthesis over the conventional FT catalyst. To the best of our knowledge, this is the first example to demonstrate experimentally that the ε-Fe2C phase can be stabilized under high-temperature FT reaction conditions. The present work provides a promising strategy to synthesize highly active and stable Fe-based FT catalysts and offers an opportunity for the study of FT reactions on pure metastable-phase iron carbides.

Torres Galvis, H. M. et al. Iron particle size effects for direct production of lower olefins from synthesis gas. J. Am. Chem. Soc. 134, 16207–16215 (2012).

“YG-1 also develops its own coatings for its products, which includes diamond, PVD and CVD coating. Currently they have just over 50 coating machines in the manufacturing plants and aim to double this number by 2020.”

Liu, X. et al. Environmental transmission electron microscopy (ETEM) studies of single iron nanoparticle carburization in synthesis gas. ACS Catal. 7, 4867–4875 (2017).

“We have more than 5 000 employees working globally across various functions of R&D, production, sales and marketing, supply chain, finance and human resources.”

Zhou, W. et al. New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO2 into hydrocarbon chemicals and fuels. Chem. Soc. Rev. 48, 3193–3228 (2019).

“We are positive about the South African market and are expecting a major growth in the region now that we have a dedicated team of sales and management staff that are operating as a fully functional subsidiary. The South African staff will have access to all of the technical know-how and developments at the South Korean headquarters, as do their colleagues around the world,” said H K Song, Founder and Chairman of YG-1.

Webster, C. E., Drago, A. R. & Zerner, M. C. Molecular dimensions for adsorptives. J. Am. Chem. Soc. 120, 5509–5516 (1998).

The ε-Fe2C@graphene catalysts with different Fe loadings all showed very high activities. The FTY value for the ε-Fe2C@graphene catalysts with Fe loadings in a range of 10–50 wt% is almost the same (~ 600 µmolCO gFe−1 s−1) under the same reaction condition. On the other hand, the FTY value of reference Fe/C catalysts decreased sharply upon increasing Fe loading probably due to the aggregation of Fe species and the oxidation of the active carbide phase under reaction conditions (Fig. 4a)40,41. The keeping of high FTY value at high Fe loading suggests that the high dispersion of ε-Fe2C phase in the ε-Fe2C@graphene catalyst is sustained at high Fe loadings and the ε-Fe2C keeps stable during FT reaction. The FTY value of ε-Fe2C@graphene with iron loading of 40.5 wt% reached 1258 μmolCO gFe−1 s−1 when the gas-hour space velocity (GHSV) was increased to 160 L gcat−1 h−1 at 613 K (Fig. 4a). The FTY values reported to date are limited at 1000 μmolCO gFe−1 s−1 (Supplementary Table 3) and the FTY value obtained using the ε-Fe2C@graphene catalyst breaks this limitation.

de Smit, E. et al. On the surface chemistry of iron oxides in reactive gas atmospheres. Angew. Chem. Int. Ed. 50, 1584–1588 (2011).

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Niemantsverdriet, J. W., Van der Kraan, A. M., Van Dijk, W. L. & Van der Baan, H. S. Behavior of metallic iron catalysts during Fischer-Tropsch synthesis studied with Mössbauer spectroscopy, X-ray diffraction, carbon content determination, and reaction kinetic measurements. J. Phys. Chem. 84, 3363–3370 (1980).

Fu, Q. & Bao, X. Surface chemistry and catalysis confined under two-dimensional materials. Chem. Soc. Rev. 46, 1842–1874 (2017).

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Herranz, T. et al. Genesis of iron carbides and their role in the synthesis of hydrocarbons from synthesis gas. J. Catal. 243, 199–211 (2006).

X-ray photoelectron spectroscopy (XPS) measurements were conducted on a VG Multilab 2000 photoelectron spectrometer using Al Kα radiation operated under vacuum (2 × 10−6 Pa) with the binding energy (BE) calibrated using the C 1s peak at 284.6 eV.

Sheng, Z. H. et al. Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis. ACS Nano 5, 4350–4358 (2011).

Puga, A. V. On the nature of active phases and sites in CO and CO2 hydrogenation catalysts. Catal. Sci. Technol. 8, 5681–5707 (2018).

The effects of a graphene layer on the surface stability and carburization feasibility of ε-Fe2C phases were investigated by ab initio atomic thermodynamics based on DFT calculations. The relative chemical potential of carbon (ΔμC) is relevant in describing the thermodynamics of iron carbides, which can be determined from the equilibrium of carburization reactions of different gas atmospheres for pretreatment or FT reaction at some temperatures and pressures. Higher temperature and lower pressure, as well as higher H2/CO ratio, result in lower ΔμC value indicating a lower carburization ability (Fig. 5a, b). Based on ΔμC, the carbon absorption energy (Eabs) can be derived for describing the carburization reaction from metallic Fe to iron carbide. The volume-normalized carbon absorption energy (Ωabs) was applied to the bulk iron carbides20.

South Korean-based company engaged in the manufacture and distribution of cutting tools also investigating the possibility of opening a local manufacturing plant.

Furthermore, the selectivity toward olefins and long-chain hydrocarbons also did not undergo significant changes during the long-term reaction. The hydrocarbon distribution over the ε-Fe2C@graphene catalyst follows the Anderson-Schulz-Flory distribution (Supplementary Fig. 9). Our Raman studies for the catalyst after reaction showed that the graphene layers and ε-Fe2C phase did not undergo significant changes (Supplementary Fig. 5). The morphology and crystalline structure of the ε-Fe2C@graphene catalyst also kept almost unchanged after 400 h reaction.

Time-on-steam evolution of CO conversion for ε-Fe2C and χ-Fe5C2 at the same conversion (~ 50%) with different GHSVs revealed that the ε-Fe2C@graphene is much more active than χ-Fe5C2 in FT synthesis, as shown in Supplementary Fig. 8. It was also found that the carburization of Fe@graphene into ε-Fe2C@graphene was completed during 50 h at GHSV of 64.0 L gcat−1 h−1. For evaluation of catalyst deactivation, we have performed long-termed FT reactions for both ε-Fe2C@graphene and un-encapsulated χ-Fe5C2 catalysts at 573 K under harsh conditions (Fig. 4b). The CO conversion underwent a significant decrease when the time-on-steam exceeded 100 h for the un-encapsulated χ-Fe5C2 catalyst and this catalyst was covered by carbon. The pressure drop across the un-encapsulated χ-Fe5C2 catalyst bed increased after 100 h and the gas flow was totally blocked at 160 h, as shown in Fig. 4b. On the other hand, the encapsulated ε-Fe2C sample was stable for more than 400 h even at a higher CO conversion (~ 95%). Further, the pressure drop across the ε-Fe2C@graphene catalyst bed was negligible even at high conversion, indicating that the coke deposition on this catalyst was significantly suppressed by the graphene layers under harsh condition.

Zhao, S. et al. Surface morphology of Hägg iron carbide (χ-Fe5C2) from ab initio atomistic thermodynamics. J. Catal. 294, 47–53 (2012).

Lyu, S., Wang, L., Li, Z. et al. Stabilization of ε-iron carbide as high-temperature catalyst under realistic Fischer–Tropsch synthesis conditions. Nat Commun 11, 6219 (2020). https://doi.org/10.1038/s41467-020-20068-5

Yang, C., Zhao, H., Hou, Y. & Ma, D. Fe5C2 nanoparticles: a facile bromide-induced synthesis and as an active phase for Fischer-Tropsch synthesis. J. Am. Chem. Soc. 134, 15814–15821 (2012).

It was once reported that the activity of ε-Fe2C nanoparticles is 4.3 times that of χ-Fe5C2 and is even comparable to that of the precious metal Ru for FT synthesis, probably owing to its excellent ability to dissociate CO29. Unfortunately, the study of the catalytic performance of ε-Fe2C under practical FT reaction conditions is limited because of its metastable state.