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Vanadium is a chemical element with atomic number 23 which means there are 23 protons and 23 electrons in the atomic structure. The chemical symbol for Vanadium is V.Vanadium is a hard, silvery grey, ductile, and malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation) stabilizes the free metal somewhat against further oxidation.
Cobalt is found in the Earth’s crust only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.
Erbium is a silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare earth element, originally found in the gadolinite mine in Ytterby in Sweden.
Praseodymium is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. Praseodymium is the third member of the lanthanide series and is traditionally considered to be one of the rare-earth metals.
Uranium is a silvery-white metal in the actinide series of the periodic table. Uranium is weakly radioactive because all isotopes of uranium are unstable, with half-lives varying between 159,200 years and 4.5 billion years. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten.
Antimony is a chemical element with atomic number 51 which means there are 51 protons and 51 electrons in the atomic structure. The chemical symbol for Antimony is Sb.Antimony is a lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite. Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name, kohl.
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Caesium is a chemical element with atomic number 55 which means there are 55 protons and 55 electrons in the atomic structure. The chemical symbol for Caesium is Cs.Caesium is a soft, silvery-gold alkali metal with a melting point of 28.5 °C, which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium.
Nitrogen is a colourless, odourless unreactive gas that forms about 78% of the earth’s atmosphere. Liquid nitrogen (made by distilling liquid air) boils at 77.4 kelvins (−195.8°C) and is used as a coolant.
Cadmium is a soft, bluish-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. In nuclear industry cadmium is commonly used as a thermal neutron absorber due to very high neutron absorption cross-section of 113Cd. 113Cd has specific absorption cross-section.
Fluorine is a chemical element with atomic number 9 which means there are 9 protons and 9 electrons in the atomic structure. The chemical symbol for Fluorine is F.Fluorine is the lightest halogen and exists as a highly toxic pale yellow diatomic gas at standard conditions. As the most electronegative element, it is extremely reactive: almost all other elements, including some noble gases, form compounds with fluorine.
Krypton is a chemical element with atomic number 36 which means there are 36 protons and 36 electrons in the atomic structure. The chemical symbol for Krypton is Kr.Krypton is a member of group 18 (noble gases) elements. A colorless, odorless, tasteless noble gas, krypton occurs in trace amounts in the atmosphere and is often used with other rare gases in fluorescent lamps.
Hydrogen is a chemical element with atomic number 1 which means there are 1 protons and 1 electrons in the atomic structure. The chemical symbol for Hydrogen is H.With a standard atomic weight of circa 1.008, hydrogen is the lightest element on the periodic table. Its monatomic form (H) is the most abundant chemical substance in the Universe, constituting roughly 75% of all baryonic mass.
Since the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Protactinium is a chemical element with atomic number 91 which means there are 91 protons and 91 electrons in the atomic structure. The chemical symbol for Protactinium is Pa.Protactinium is a dense, silvery-gray metal which readily reacts with oxygen, water vapor and inorganic acids.
Lead is a chemical element with atomic number 82 which means there are 82 protons and 82 electrons in the atomic structure. The chemical symbol for Lead is Pb.Lead is a heavy metal that is denser than most common materials. Lead is soft and malleable, and has a relatively low melting point. Lead is widely used as a gamma shield. Major advantage of lead shield is in its compactness due to its higher density. Lead has the highest atomic number of any stable element and concludes three major decay chains of heavier elements.
Scandium is a silvery-white metallic d-block element, it has historically been sometimes classified as a rare-earth element, together with yttrium and the lanthanides.
and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Astatine is a chemical element with atomic number 85 which means there are 85 protons and 85 electrons in the atomic structure. The chemical symbol for Astatine is At.Astatine is the rarest naturally occurring element on the Earth’s crust. It occurs on Earth as the decay product of various heavier elements. The bulk properties of astatine are not known with any certainty.
Bromine is a chemical element with atomic number 35 which means there are 35 protons and 35 electrons in the atomic structure. The chemical symbol for Bromine is Br.Bromine is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas. Its properties are thus intermediate between those of chlorine and iodine.
Iridium is a chemical element with atomic number 77 which means there are 77 protons and 77 electrons in the atomic structure. The chemical symbol for Iridium is Ir.Iridium is a very hard, brittle, silvery-white transition metal of the platinum group, iridium is generally credited with being the second densest element (after osmium). It is also the most corrosion-resistant metal, even at temperatures as high as 2000 °C.
Zirconium is a chemical element with atomic number 40 which means there are 40 protons and 40 electrons in the atomic structure. The chemical symbol for Zirconium is Zr. Zirconium is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium is widely used as a cladding for nuclear reactor fuels.
Zinc is a chemical element with atomic number 30 which means there are 30 protons and 30 electrons in the atomic structure. The chemical symbol for Zinc is Zn.In some respects zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.
Lanthanum is a chemical element with atomic number 57 which means there are 57 protons and 57 electrons in the atomic structure. The chemical symbol for Lanthanum is La.Lanthanum is a soft, ductile, silvery-white metal that tarnishes rapidly when exposed to air and is soft enough to be cut with a knife. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. It is also sometimes considered the first element of the 6th-period transition metals and is traditionally counted among the rare earth elements.
Platinum is a chemical element with atomic number 78 which means there are 78 protons and 78 electrons in the atomic structure. The chemical symbol for Platinum is Pt. Platinum is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Platinum is one of the least reactive metals. It has remarkable resistance to corrosion, even at high temperatures, and is therefore considered a noble metal. Platinum is used in catalytic converters, laboratory equipment, electrical contacts and electrodes, platinum resistance thermometers, dentistry equipment, and jewelry.
Ruthenium is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemicals.
Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity, behind only oxygen and fluorine.
Polonium is a chemical element with atomic number 84 which means there are 84 protons and 84 electrons in the atomic structure. The chemical symbol for Polonium is Po.Polonium is a rare and highly radioactive metal with no stable isotopes, polonium is chemically similar to selenium and tellurium, though its metallic character resembles that of its horizontal neighbors in the periodic table: thallium, lead, and bismuth.
The atom consist of a small but massive nucleus surrounded by a cloud of rapidly moving electrons. The nucleus is composed of protons and neutrons. Total number of protons in the nucleus is called the atomic number of the atom and is given the symbol Z. The total electrical charge of the nucleus is therefore +Ze, where e (elementary charge) equals to 1,602 x 10-19 coulombs. In a neutral atom there are as many electrons as protons moving about nucleus. It is the electrons that are responsible for the chemical bavavior of atoms, and which identify the various chemical elements.See also: Atomic Number – Does it conserve in a nuclear reaction?Atomic Number and Chemical PropertiesEvery solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.Density of NickelDensity of Nickel is 8.908g/cm3.Typical densities of various substances are at atmospheric pressure.Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
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Silicon is a chemical element with atomic number 14 which means there are 14 protons and 14 electrons in the atomic structure. The chemical symbol for Silicon is Si.Silicon is a hard and brittle crystalline solid with a blue-grey metallic lustre, it is a tetravalent metalloid and semiconductor.
Thorium metal is silvery and tarnishes black when exposed to air, forming the dioxide. Thorium is moderately hard, malleable, and has a high melting point. Thorium is a naturally-occurring element and it is estimated to be about three times more abundant than uranium. Thorium is commonly found in monazite sands (rare earth metals containing phosphate mineral).
Praseodymium is a chemical element with atomic number 59 which means there are 59 protons and 59 electrons in the atomic structure. The chemical symbol for Praseodymium is Pr.Praseodymium is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. Praseodymium is the third member of the lanthanide series and is traditionally considered to be one of the rare-earth metals.
“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Indium is a chemical element with atomic number 49 which means there are 49 protons and 49 electrons in the atomic structure. The chemical symbol for Indium is In.Indium is a post-transition metal that makes up 0.21 parts per million of the Earth’s crust. Very soft and malleable, indium has a melting point higher than sodium and gallium, but lower than lithium and tin. Chemically, indium is similar to gallium and thallium.
X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Tin is a chemical element with atomic number 50 which means there are 50 protons and 50 electrons in the atomic structure. The chemical symbol for Tin is Sn.Tin is a post-transition metal in group 14 of the periodic table. It is obtained chiefly from the mineral cassiterite, which contains tin dioxide. The first alloy used on a large scale was bronze, made of tin and copper, from as early as 3000 BC.
Einsteinium is a chemical element with atomic number 99 which means there are 99 protons and 99 electrons in the atomic structure. The chemical symbol for Einsteinium is Es.Einsteinium is the seventh transuranic element, and an actinide.
Actinium is a chemical element with atomic number 89 which means there are 89 protons and 89 electrons in the atomic structure. The chemical symbol for Actinium is Ac.Actinium is a soft, silvery-white radioactive metal. Actinium gave the name to the actinide series, a group of 15 similar elements between actinium and lawrencium in the periodic table.
the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Chromium is a steely-grey, lustrous, hard and brittle metal4 which takes a high polish, resists tarnishing, and has a high melting point. A major development was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel.
Potassium was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals. All of the alkali metals have a single valence electron in the outer electron shell, which is easily removed to create an ion with a positive charge – a cation, which combines with anions to form salts. Naturally occurring potassium is composed of three isotopes, of which 40K is radioactive.
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Typical densities of various substances are at atmospheric pressure.Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Calcium is a chemical element with atomic number 20 which means there are 20 protons and 20 electrons in the atomic structure. The chemical symbol for Calcium is Ca.Calcium is an alkaline earth metal, it is a reactive pale yellow metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth’s crust and the third most abundant metal, after iron and aluminium.
Sulfur is abundant, multivalent, and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow crystalline solid at room temperature. Chemically, sulfur reacts with all elements except for gold, platinum, iridium, tellurium, and the noble gases.
Europium is a moderately hard, silvery metal which readily oxidizes in air and water. Being a typical member of the lanthanide series, europium usually assumes the oxidation state +3. Europium is one of the least abundant elements in the universe. Only about 5×10−8% of all matter in the universe is europium.
Iron is a metal in the first transition series. It is by mass the most common element on Earth, forming much of Earth’s outer and inner core. It is the fourth most common element in the Earth’s crust. Its abundance in rocky planets like Earth is due to its abundant production by fusion in high-mass stars.
Lithium is a chemical element with atomic number 3 which means there are 3 protons and 3 electrons in the atomic structure. The chemical symbol for Lithium is Li.It is a soft, silvery-white alkali metal. Under standard conditions, it is the lightest metal and the lightest solid element. Like all alkali metals, lithium is highly reactive and flammable, and is stored in mineral oil.
Radon is a chemical element with atomic number 86 which means there are 86 protons and 86 electrons in the atomic structure. The chemical symbol for Radon is Rn.Radon is a radioactive, colorless, odorless, tasteless noble gas. Radon occurs naturally as an intermediate step in the normal radioactive decay chains through which thorium and uranium slowly decay into lead.
Antimony is a lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite. Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name, kohl.
Selenium is a nonmetal with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, and also has similarities to arsenic. It rarely occurs in its elemental state or as pure ore compounds in the Earth’s crust.
Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Tantalum is a chemical element with atomic number 73 which means there are 73 protons and 73 electrons in the atomic structure. The chemical symbol for Tantalum is Ta.Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion-resistant.
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Oxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Neon is a chemical element with atomic number 10 which means there are 10 protons and 10 electrons in the atomic structure. The chemical symbol for Neon is Ne.Neon is a colorless, odorless, inert monatomic gas under standard conditions, with about two-thirds the density of air.
Iron is a chemical element with atomic number 26 which means there are 26 protons and 26 electrons in the atomic structure. The chemical symbol for Iron is Fe.Iron is a metal in the first transition series. It is by mass the most common element on Earth, forming much of Earth’s outer and inner core. It is the fourth most common element in the Earth’s crust. Its abundance in rocky planets like Earth is due to its abundant production by fusion in high-mass stars.
If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.
Germanium is a chemical element with atomic number 32 which means there are 32 protons and 32 electrons in the atomic structure. The chemical symbol for Germanium is Ge.Germanium is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. Pure germanium is a semiconductor with an appearance similar to elemental silicon.
Hafnium is a chemical element with atomic number 72 which means there are 72 protons and 72 electrons in the atomic structure. The chemical symbol for Hafnium is Hf. Hafnium is a lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Hafnium’s large neutron capture cross-section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors.
As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Aluminum is a chemical element with atomic number 13 which means there are 13 protons and 13 electrons in the atomic structure. The chemical symbol for Aluminum is Al.Aluminium is a silvery-white, soft, nonmagnetic, ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth’s crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below.
Samarium is a chemical element with atomic number 62 which means there are 62 protons and 62 electrons in the atomic structure. The chemical symbol for Samarium is Sm. Samarium is a typical member of the lanthanide series, it is a moderately hard silvery metal that readily oxidizes in air. The name samarium is after the mineral samarskite from which it was isolated. Although classified as a rare earth element, samarium is the 40th most abundant element in the Earth’s crust and is more common than such metals as tin. In nuclear industry, especially natural and artificial samarium 149 has an important impact on the operation of a nuclear reactor.
Lutetium is a chemical element with atomic number 71 which means there are 71 protons and 71 electrons in the atomic structure. The chemical symbol for Lutetium is Lu.Lutetium is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earths.
Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Aluminium is a silvery-white, soft, nonmagnetic, ductile metal in the boron group. By mass, aluminium makes up about 8% of the Earth’s crust; it is the third most abundant element after oxygen and silicon and the most abundant metal in the crust, though it is less common in the mantle below.
Rubidium is a soft, silvery-white metallic element of the alkali metal group, with an atomic mass of 85.4678. Elemental rubidium is highly reactive, with properties similar to those of other alkali metals, including rapid oxidation in air.
Silver is a soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth’s crust in the pure, free elemental form (“native silver”), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite.
Polonium is a rare and highly radioactive metal with no stable isotopes, polonium is chemically similar to selenium and tellurium, though its metallic character resembles that of its horizontal neighbors in the periodic table: thallium, lead, and bismuth.
Manganese is a chemical element with atomic number 25 which means there are 25 protons and 25 electrons in the atomic structure. The chemical symbol for Manganese is Mn.Manganese is a metal with important industrial metal alloy uses, particularly in stainless steels.
ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Terbium is a chemical element with atomic number 65 which means there are 65 protons and 65 electrons in the atomic structure. The chemical symbol for Terbium is Tb.Terbium is a silvery-white, rare earth metal that is malleable, ductile, and soft enough to be cut with a knife. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas.
Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Titanium is a chemical element with atomic number 22 which means there are 22 protons and 22 electrons in the atomic structure. The chemical symbol for Titanium is Ti. Titanium is a lustrous transition metal with a silver color, low density, and high strength. Titanium is resistant to corrosion in sea water, aqua regia, and chlorine. Titanium can be used in surface condensers. These condensers use tubes that are usually made of stainless steel, copper alloys, or titanium depending on several selection criteria (such as thermal conductivity or corrosion resistance). Titanium condenser tubes are usually the best technical choice, however titanium is very expensive material.
Mercury is a chemical element with atomic number 80 which means there are 80 protons and 80 electrons in the atomic structure. The chemical symbol for Mercury is Hg.Mercury is commonly known as quicksilver and was formerly named hydrargyrum. Mercury is a heavy, silvery d-block element, mercury is the only metallic element that is liquid at standard conditions for temperature and pressure.
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Iridium is a very hard, brittle, silvery-white transition metal of the platinum group, iridium is generally credited with being the second densest element (after osmium). It is also the most corrosion-resistant metal, even at temperatures as high as 2000 °C.
It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
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The periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Technetium is the lightest element whose isotopes are all radioactive; none are stable. Nearly all technetium is produced synthetically, and only minute amounts are found in the Earth’s crust. The chemical properties of this silvery gray, crystalline transition metal are intermediate between rhenium and manganese.
Significant concentrations of boron occur on the Earth in compounds known as the borate minerals. There are over 100 different borate minerals, but the most common are: borax, kernite, ulexite etc. Natural boron consists primarily of two stable isotopes, 11B (80.1%) and 10B (19.9%). In nuclear industry boron is commonly used as a neutron absorber due to the high neutron cross-section of isotope 10B.
Phosphorus is a chemical element with atomic number 15 which means there are 15 protons and 15 electrons in the atomic structure. The chemical symbol for Phosphorus is P.As an element, phosphorus exists in two major forms—white phosphorus and red phosphorus—but because it is highly reactive, phosphorus is never found as a free element on Earth. At 0.099%, phosphorus is the most abundant pnictogen in the Earth’s crust.
Niobium is a soft, grey, ductile transition metal, often found in the minerals pyrochlore (the main commercial source for niobium) and columbite.
Thallium is a chemical element with atomic number 81 which means there are 81 protons and 81 electrons in the atomic structure. The chemical symbol for Thallium is Tl.Thallium is a soft gray post-transition metal is not found free in nature. Commercially, thallium is produced as a byproduct from refining of heavy metal sulfide ores. Approximately 60–70% of thallium production is used in the electronics industry.
Mendelevium is a metallic radioactive transuranic element in the actinide series, it is the first element that currently cannot be produced in macroscopic quantities.
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Plutonium is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized.
Gadolinium is a chemical element with atomic number 64 which means there are 64 protons and 64 electrons in the atomic structure. The chemical symbol for Gadolinium is Gd.Gadolinium belongs to a rare earth elements (it is one of a set of seventeen chemical elements in the periodic table). In nuclear industry gadolinium is commonly used as a neutron absorber due to very high neutron absorbtion cross-section of two isotopes 155Gd and 157Gd. In fact their absorption cross-sections are the highest among all stable isotopes.
Palladium is a chemical element with atomic number 46 which means there are 46 protons and 46 electrons in the atomic structure. The chemical symbol for Palladium is Pd.Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). These have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.
See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
In some respects zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.
Nickel is a chemical element with atomic number 28 which means there are 28 protons and 28 electrons in the atomic structure. The chemical symbol for Nickel is Ni.Nickel is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile.
In other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
With a standard atomic weight of circa 1.008, hydrogen is the lightest element on the periodic table. Its monatomic form (H) is the most abundant chemical substance in the Universe, constituting roughly 75% of all baryonic mass.
Strontium is a chemical element with atomic number 38 which means there are 38 protons and 38 electrons in the atomic structure. The chemical symbol for Strontium is Sr.Strontium is an alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly reactive chemically.
Caesium is a soft, silvery-gold alkali metal with a melting point of 28.5 °C, which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium.
Nickel is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile.
Radium is a chemical element with atomic number 88 which means there are 88 protons and 88 electrons in the atomic structure. The chemical symbol for Radium is Ra.Pure radium is silvery-white alkaline earth metal. All isotopes of radium are highly radioactive, with the most stable isotope being radium-226.
In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
In chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Sodium is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation.
In general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Nickel is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile.
Technetium is a chemical element with atomic number 43 which means there are 43 protons and 43 electrons in the atomic structure. The chemical symbol for Technetium is Tc.Technetium is the lightest element whose isotopes are all radioactive; none are stable. Nearly all technetium is produced synthetically, and only minute amounts are found in the Earth’s crust. The chemical properties of this silvery gray, crystalline transition metal are intermediate between rhenium and manganese.
As an element, phosphorus exists in two major forms—white phosphorus and red phosphorus—but because it is highly reactive, phosphorus is never found as a free element on Earth. At 0.099%, phosphorus is the most abundant pnictogen in the Earth’s crust.
Bismuth is a brittle metal with a silvery white color when freshly produced, but surface oxidation can give it a pink tinge. Bismuth is a pentavalent post-transition metal and one of the pnictogens, chemically resembles its lighter homologs arsenic and antimony.
Electronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Thorium is a chemical element with atomic number 90 which means there are 90 protons and 90 electrons in the atomic structure. The chemical symbol for Thorium is Th.Thorium metal is silvery and tarnishes black when exposed to air, forming the dioxide. Thorium is moderately hard, malleable, and has a high melting point. Thorium is a naturally-occurring element and it is estimated to be about three times more abundant than uranium. Thorium is commonly found in monazite sands (rare earth metals containing phosphate mineral).
Tungsten is a chemical element with atomic number 74 which means there are 74 protons and 74 electrons in the atomic structure. The chemical symbol for Tungsten is W.Tungsten is a rare metal found naturally on Earth almost exclusively in chemical compounds. Tungsten is an intrinsically brittle and hard material, making it difficult to work.
Magnesium is a shiny gray solid which bears a close physical resemblance to the other five elements in the second column (group 2, or alkaline earth metals) of the periodic table: all group 2 elements have the same electron configuration in the outer electron shell and a similar crystal structure.
Barium is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most probable fission fragment masses are around mass 95 (Krypton) and 137 (Barium).
Mercury is commonly known as quicksilver and was formerly named hydrargyrum. Mercury is a heavy, silvery d-block element, mercury is the only metallic element that is liquid at standard conditions for temperature and pressure.
The first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
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The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Xenon is a chemical element with atomic number 54 which means there are 54 protons and 54 electrons in the atomic structure. The chemical symbol for Xenon is Xe.Xenon is a colorless, dense, odorless noble gas found in the Earth’s atmosphere in trace amounts. The name xenon for this gas comes from the Greek word ξένον [xenon], neuter singular form of ξένος [xenos], meaning ‘foreign(er)’, ‘strange(r)’, or ‘guest’. In nuclear industry, especially artificial xenon 135 has a tremendous impact on the operation of a nuclear reactor.
In words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Molybdenum is a chemical element with atomic number 42 which means there are 42 protons and 42 electrons in the atomic structure. The chemical symbol for Molybdenum is Mo.Molybdenum a silvery metal with a gray cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys.
Yttrium is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a “rare-earth element”.
Yttrium is a chemical element with atomic number 39 which means there are 39 protons and 39 electrons in the atomic structure. The chemical symbol for Yttrium is Y.Yttrium is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a “rare-earth element”.
Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Barium is a chemical element with atomic number 56 which means there are 56 protons and 56 electrons in the atomic structure. The chemical symbol for Barium is Ba.Barium is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most probable fission fragment masses are around mass 95 (Krypton) and 137 (Barium).
Oxygen is a colourless, odourless reactive gas, the chemical element of atomic number 8 and the life-supporting component of the air. It is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. By mass, oxygen is the third-most abundant element in the universe, after hydrogen and helium.
Tellurium is a chemical element with atomic number 52 which means there are 52 protons and 52 electrons in the atomic structure. The chemical symbol for Tellurium is Te.Tellurium is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the universe as a whole than on Earth. Its extreme rarity in the Earth’s crust, comparable to that of platinum.
Iodine is the heaviest of the stable halogens, it exists as a lustrous, purple-black metallic solid at standard conditions that sublimes readily to form a violet gas. Iodine is the least abundant of the stable halogens, being the sixty-first most abundant element. It is even less abundant than the so-called rare earths. It is the heaviest essential mineral nutrient.
Helium is a chemical element with atomic number 2 which means there are 2 protons and 2 electrons in the atomic structure. The chemical symbol for Helium is He.It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas, the first in the noble gas group in the periodic table. Its boiling point is the lowest among all the elements.
Tin is a post-transition metal in group 14 of the periodic table. It is obtained chiefly from the mineral cassiterite, which contains tin dioxide. The first alloy used on a large scale was bronze, made of tin and copper, from as early as 3000 BC.
Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Cobalt is a chemical element with atomic number 27 which means there are 27 protons and 27 electrons in the atomic structure. The chemical symbol for Cobalt is Co.Cobalt is found in the Earth’s crust only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.
Actinium is a soft, silvery-white radioactive metal. Actinium gave the name to the actinide series, a group of 15 similar elements between actinium and lawrencium in the periodic table.
Argon is the third-most abundant gas in the Earth’s atmosphere, at 0.934% (9340 ppmv). Argon is mostly used as an inert shielding gas in welding and other high-temperature industrial processes where ordinarily unreactive substances become reactive; for example, an argon atmosphere is used in graphite electric furnaces to prevent the graphite from burning.
Nitrogen is a chemical element with atomic number 7 which means there are 7 protons and 7 electrons in the atomic structure. The chemical symbol for Nitrogen is N.Nitrogen is a colourless, odourless unreactive gas that forms about 78% of the earth’s atmosphere. Liquid nitrogen (made by distilling liquid air) boils at 77.4 kelvins (−195.8°C) and is used as a coolant.
In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Tellurium is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur. It is occasionally found in native form as elemental crystals. Tellurium is far more common in the universe as a whole than on Earth. Its extreme rarity in the Earth’s crust, comparable to that of platinum.
Molybdenum a silvery metal with a gray cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys.
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It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.Density of NickelDensity of Nickel is 8.908g/cm3.Typical densities of various substances are at atmospheric pressure.Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Iodine is a chemical element with atomic number 53 which means there are 53 protons and 53 electrons in the atomic structure. The chemical symbol for Iodine is I.Iodine is the heaviest of the stable halogens, it exists as a lustrous, purple-black metallic solid at standard conditions that sublimes readily to form a violet gas. Iodine is the least abundant of the stable halogens, being the sixty-first most abundant element. It is even less abundant than the so-called rare earths. It is the heaviest essential mineral nutrient.
In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.
Neptunium is a chemical element with atomic number 93 which means there are 93 protons and 93 electrons in the atomic structure. The chemical symbol for Neptunium is Np.Neptunium metal is silvery and tarnishes when exposed to air. Neptunium is the first transuranic element.
Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Lead is a heavy metal that is denser than most common materials. Lead is soft and malleable, and has a relatively low melting point. Lead is widely used as a gamma shield. Major advantage of lead shield is in its compactness due to its higher density. Lead has the highest atomic number of any stable element and concludes three major decay chains of heavier elements.
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Rhenium is a chemical element with atomic number 75 which means there are 75 protons and 75 electrons in the atomic structure. The chemical symbol for Rhenium is Re.Rhenium is a silvery-white, heavy, third-row transition metal in group 7 of the periodic table.
Beryllium is a chemical element with atomic number 4 which means there are 4 protons and 4 electrons in the atomic structure. The chemical symbol for Beryllium is Be.Beryllium is a hard, grayish metal naturally found in mineral rocks, coal, soil, and volcanic dust. The commercial use of beryllium requires the use of appropriate dust control equipment and industrial controls at all times because of the toxicity of inhaled beryllium-containing dusts that can cause a chronic life-threatening allergic disease in some people called berylliosis.
Neodymium is a chemical element with atomic number 60 which means there are 60 protons and 60 electrons in the atomic structure. The chemical symbol for Neodymium is Nd.Neodymium is a soft silvery metal that tarnishes in air. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Although neodymium is classed as a rare earth, it is a fairly common element.
Pure radium is silvery-white alkaline earth metal. All isotopes of radium are highly radioactive, with the most stable isotope being radium-226.
Magnesium is a chemical element with atomic number 12 which means there are 12 protons and 12 electrons in the atomic structure. The chemical symbol for Magnesium is Mg.Magnesium is a shiny gray solid which bears a close physical resemblance to the other five elements in the second column (group 2, or alkaline earth metals) of the periodic table: all group 2 elements have the same electron configuration in the outer electron shell and a similar crystal structure.
Fermium is a member of the actinide series. It is the heaviest element that can be formed by neutron bombardment of lighter elements, and hence the last element that can be prepared in macroscopic quantities.
Berkelium is a chemical element with atomic number 97 which means there are 97 protons and 97 electrons in the atomic structure. The chemical symbol for Berkelium is Bk.Berkelium is a member of the actinide and transuranium element series.
Krypton is a member of group 18 (noble gases) elements. A colorless, odorless, tasteless noble gas, krypton occurs in trace amounts in the atmosphere and is often used with other rare gases in fluorescent lamps.
Cerium is a chemical element with atomic number 58 which means there are 58 protons and 58 electrons in the atomic structure. The chemical symbol for Cerium is Ce.Cerium is a soft, ductile and silvery-white metal that tarnishes when exposed to air, and it is soft enough to be cut with a knife. Cerium is the second element in the lanthanide series. Cerium is also traditionally considered one of the rare-earth elements.
Promethium is one of only two such elements that are followed in the periodic table by elements with stable forms. All of its isotopes are radioactive. In nuclear reactors, promethium equilibrium exists in power operation. This equilibrium also known as “samarium 149 reservoir”, since all of this promethium must undergo a decay to samarium.
Copper is a chemical element with atomic number 29 which means there are 29 protons and 29 electrons in the atomic structure. The chemical symbol for Copper is Cu.Copper is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a reddish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins.
Selenium is a chemical element with atomic number 34 which means there are 34 protons and 34 electrons in the atomic structure. The chemical symbol for Selenium is Se.Selenium is a nonmetal with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, and also has similarities to arsenic. It rarely occurs in its elemental state or as pure ore compounds in the Earth’s crust.
Bromine is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas. Its properties are thus intermediate between those of chlorine and iodine.
Silicon is a hard and brittle crystalline solid with a blue-grey metallic lustre, it is a tetravalent metalloid and semiconductor.
is a rare earth element with a metallic silver luster. Dysprosium is used for its high thermal neutron absorption cross-section in making control rods in nuclear reactors, for its high magnetic susceptibility in data storage applications.
Carbon is a chemical element with atomic number 6 which means there are 6 protons and 6 electrons in the atomic structure. The chemical symbol for Carbon is C.It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. Carbon is one of the few elements known since antiquity. Carbon is the 15th most abundant element in the Earth’s crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen.
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In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
2021713 — Here, we will be looking at issues and challenges faced when machining stainless steel and how to overcome them.
Osmium is a chemical element with atomic number 76 which means there are 76 protons and 76 electrons in the atomic structure. The chemical symbol for Osmium is Os. Osmium is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mostly in platinum ores. Osmium is the densest naturally occurring element, with a density of 22.59 g/cm3. But its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.
Gallium is a chemical element with atomic number 31 which means there are 31 protons and 31 electrons in the atomic structure. The chemical symbol for Gallium is Ga.Gallium has similarities to the other metals of the group, aluminium, indium, and thallium. Gallium does not occur as a free element in nature, but as gallium(III) compounds in trace amounts in zinc ores and in bauxite.
Radon is a radioactive, colorless, odorless, tasteless noble gas. Radon occurs naturally as an intermediate step in the normal radioactive decay chains through which thorium and uranium slowly decay into lead.
Tungsten carbide cold heading dies for fasteners,high impact resistance,toughness ,wear resistance,and quality consistency.You are encouraged to use our ...
Americium is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was named after the Americas.
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Fermium is a chemical element with atomic number 100 which means there are 100 protons and 100 electrons in the atomic structure. The chemical symbol for Fermium is Fm.Fermium is a member of the actinide series. It is the heaviest element that can be formed by neutron bombardment of lighter elements, and hence the last element that can be prepared in macroscopic quantities.
Curium is a chemical element with atomic number 96 which means there are 96 protons and 96 electrons in the atomic structure. The chemical symbol for Curium is Cm.Curium is a hard, dense, silvery metal with a relatively high melting point and boiling point for an actinide.
Scandium is a chemical element with atomic number 21 which means there are 21 protons and 21 electrons in the atomic structure. The chemical symbol for Scandium is Sc.Scandium is a silvery-white metallic d-block element, it has historically been sometimes classified as a rare-earth element, together with yttrium and the lanthanides.
Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.
Germanium is a lustrous, hard, grayish-white metalloid in the carbon group, chemically similar to its group neighbors tin and silicon. Pure germanium is a semiconductor with an appearance similar to elemental silicon.
Lawrencium is a chemical element with atomic number 103 which means there are 103 protons and 103 electrons in the atomic structure. The chemical symbol for Lawrencium is Lr.Lawrencium is the final member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles.
Copper is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a reddish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins.
Cerium is a soft, ductile and silvery-white metal that tarnishes when exposed to air, and it is soft enough to be cut with a knife. Cerium is the second element in the lanthanide series. Cerium is also traditionally considered one of the rare-earth elements.
Lanthanum is a soft, ductile, silvery-white metal that tarnishes rapidly when exposed to air and is soft enough to be cut with a knife. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. It is also sometimes considered the first element of the 6th-period transition metals and is traditionally counted among the rare earth elements.
Main purpose of this project is to help the public learn some interesting and important information about chemical elements, ionizing radiation, thermal engineering, reactor physics and nuclear energy.
As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Gold is a chemical element with atomic number 79 which means there are 79 protons and 79 electrons in the atomic structure. The chemical symbol for Gold is Au.Gold is a bright, slightly reddish yellow, dense, soft, malleable, and ductile metal. Gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold is thought to have been produced in supernova nucleosynthesis, from the collision of neutron stars.
Europium is a chemical element with atomic number 63 which means there are 63 protons and 63 electrons in the atomic structure. The chemical symbol for Europium is Eu.Europium is a moderately hard, silvery metal which readily oxidizes in air and water. Being a typical member of the lanthanide series, europium usually assumes the oxidation state +3. Europium is one of the least abundant elements in the universe. Only about 5×10−8% of all matter in the universe is europium.
Neodymium is a soft silvery metal that tarnishes in air. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Although neodymium is classed as a rare earth, it is a fairly common element.
Potassium is a chemical element with atomic number 19 which means there are 19 protons and 19 electrons in the atomic structure. The chemical symbol for Potassium is K.Potassium was first isolated from potash, the ashes of plants, from which its name derives. In the periodic table, potassium is one of the alkali metals. All of the alkali metals have a single valence electron in the outer electron shell, which is easily removed to create an ion with a positive charge – a cation, which combines with anions to form salts. Naturally occurring potassium is composed of three isotopes, of which 40K is radioactive.
Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Ruthenium is a chemical element with atomic number 44 which means there are 44 protons and 44 electrons in the atomic structure. The chemical symbol for Ruthenium is Ru.Ruthenium is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is inert to most other chemicals.
Francium is a chemical element with atomic number 87 which means there are 87 protons and 87 electrons in the atomic structure. The chemical symbol for Francium is Fr.Francium is an alkali metal, that has one valence electron. Francium is the second-least electronegative element, behind only caesium, and is the second rarest naturally occurring element (after astatine). Francium is a highly radioactive metal that decays into astatine, radium, and radon.
An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Nobelium is the tenth transuranic element and is the penultimate member of the actinide series. Like all elements with atomic number over 100, nobelium can only be produced in particle accelerators by bombarding lighter elements with charged particles.
Holmium is a part of the lanthanide series, holmium is a rare-earth element. Holmium is a relatively soft and malleable silvery-white metal.
Xenon is a colorless, dense, odorless noble gas found in the Earth’s atmosphere in trace amounts. The name xenon for this gas comes from the Greek word ξένον [xenon], neuter singular form of ξένος [xenos], meaning ‘foreign(er)’, ‘strange(r)’, or ‘guest’. In nuclear industry, especially artificial xenon 135 has a tremendous impact on the operation of a nuclear reactor.
Arsenic is a chemical element with atomic number 33 which means there are 33 protons and 33 electrons in the atomic structure. The chemical symbol for Arsenic is As.Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid.
Thulium is an easily workable metal with a bright silvery-gray luster. It is fairly soft and slowly tarnishes in air. Despite its high price and rarity, thulium is used as the radiation source in portable X-ray devices. Thulium is the thirteenth and third-last element in the lanthanide series.
Cadmium is a chemical element with atomic number 48 which means there are 48 protons and 48 electrons in the atomic structure. The chemical symbol for Cadmium is Cd.Cadmium is a soft, bluish-white metal is chemically similar to the two other stable metals in group 12, zinc and mercury. In nuclear industry cadmium is commonly used as a thermal neutron absorber due to very high neutron absorption cross-section of 113Cd. 113Cd has specific absorption cross-section.
The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Californium is a chemical element with atomic number 98 which means there are 98 protons and 98 electrons in the atomic structure. The chemical symbol for Californium is Cf.Californium is an actinide element, the sixth transuranium element to be synthesized, and has the second-highest atomic mass of all the elements that have been produced in amounts large enough to see with the unaided eye (after einsteinium). The most commonly used spontaneous fission neutron source is the radioactive isotope californium-252.
Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:
The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Calcium is an alkaline earth metal, it is a reactive pale yellow metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to its heavier homologues strontium and barium. It is the fifth most abundant element in Earth’s crust and the third most abundant metal, after iron and aluminium.
Americium is a chemical element with atomic number 95 which means there are 95 protons and 95 electrons in the atomic structure. The chemical symbol for Americium is Am.Americium is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was named after the Americas.
It is a soft, silvery-white alkali metal. Under standard conditions, it is the lightest metal and the lightest solid element. Like all alkali metals, lithium is highly reactive and flammable, and is stored in mineral oil.
It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas, the first in the noble gas group in the periodic table. Its boiling point is the lowest among all the elements.
Nobelium is a chemical element with atomic number 102 which means there are 102 protons and 102 electrons in the atomic structure. The chemical symbol for Nobelium is No.Nobelium is the tenth transuranic element and is the penultimate member of the actinide series. Like all elements with atomic number over 100, nobelium can only be produced in particle accelerators by bombarding lighter elements with charged particles.
Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Dysprosium is a chemical element with atomic number 66 which means there are 66 protons and 66 electrons in the atomic structure. The chemical symbol for Dysprosium is Dy.is a rare earth element with a metallic silver luster. Dysprosium is used for its high thermal neutron absorption cross-section in making control rods in nuclear reactors, for its high magnetic susceptibility in data storage applications.
Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.
Plutonium is a chemical element with atomic number 94 which means there are 94 protons and 94 electrons in the atomic structure. The chemical symbol for Plutonium is Pu.Plutonium is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized.
Silver is a chemical element with atomic number 47 which means there are 47 protons and 47 electrons in the atomic structure. The chemical symbol for Silver is Ag.Silver is a soft, white, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. The metal is found in the Earth’s crust in the pure, free elemental form (“native silver”), as an alloy with gold and other metals, and in minerals such as argentite and chlorargyrite.
The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Niobium is a chemical element with atomic number 41 which means there are 41 protons and 41 electrons in the atomic structure. The chemical symbol for Niobium is Nb.Niobium is a soft, grey, ductile transition metal, often found in the minerals pyrochlore (the main commercial source for niobium) and columbite.
Chlorine is a chemical element with atomic number 17 which means there are 17 protons and 17 electrons in the atomic structure. The chemical symbol for Chlorine is Cl.Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity, behind only oxygen and fluorine.
Gold is a bright, slightly reddish yellow, dense, soft, malleable, and ductile metal. Gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold is thought to have been produced in supernova nucleosynthesis, from the collision of neutron stars.
Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
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Lawrencium is the final member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles.
Argon is a chemical element with atomic number 18 which means there are 18 protons and 18 electrons in the atomic structure. The chemical symbol for Argon is Ar.Argon is the third-most abundant gas in the Earth’s atmosphere, at 0.934% (9340 ppmv). Argon is mostly used as an inert shielding gas in welding and other high-temperature industrial processes where ordinarily unreactive substances become reactive; for example, an argon atmosphere is used in graphite electric furnaces to prevent the graphite from burning.
Tungsten is a rare metal found naturally on Earth almost exclusively in chemical compounds. Tungsten is an intrinsically brittle and hard material, making it difficult to work.
Strontium is an alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly reactive chemically.
Gallium has similarities to the other metals of the group, aluminium, indium, and thallium. Gallium does not occur as a free element in nature, but as gallium(III) compounds in trace amounts in zinc ores and in bauxite.
Boron is a chemical element with atomic number 5 which means there are 5 protons and 5 electrons in the atomic structure. The chemical symbol for Boron is B.Significant concentrations of boron occur on the Earth in compounds known as the borate minerals. There are over 100 different borate minerals, but the most common are: borax, kernite, ulexite etc. Natural boron consists primarily of two stable isotopes, 11B (80.1%) and 10B (19.9%). In nuclear industry boron is commonly used as a neutron absorber due to the high neutron cross-section of isotope 10B.
Melting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Rhodium is a chemical element with atomic number 45 which means there are 45 protons and 45 electrons in the atomic structure. The chemical symbol for Rhodium is Rh.Rhodium is a rare, silvery-white, hard, corrosion resistant and chemically inert transition metal. It is a noble metal and a member of the platinum group.
Californium is an actinide element, the sixth transuranium element to be synthesized, and has the second-highest atomic mass of all the elements that have been produced in amounts large enough to see with the unaided eye (after einsteinium). The most commonly used spontaneous fission neutron source is the radioactive isotope californium-252.
Beryllium is a hard, grayish metal naturally found in mineral rocks, coal, soil, and volcanic dust. The commercial use of beryllium requires the use of appropriate dust control equipment and industrial controls at all times because of the toxicity of inhaled beryllium-containing dusts that can cause a chronic life-threatening allergic disease in some people called berylliosis.
Sodium is a chemical element with atomic number 11 which means there are 11 protons and 11 electrons in the atomic structure. The chemical symbol for Sodium is Na.Sodium is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table, because it has a single electron in its outer shell that it readily donates, creating a positively charged atom—the Na+ cation.
Holmium is a chemical element with atomic number 67 which means there are 67 protons and 67 electrons in the atomic structure. The chemical symbol for Holmium is Ho.Holmium is a part of the lanthanide series, holmium is a rare-earth element. Holmium is a relatively soft and malleable silvery-white metal.
Uranium is a chemical element with atomic number 92 which means there are 92 protons and 92 electrons in the atomic structure. The chemical symbol for Uranium is U.Uranium is a silvery-white metal in the actinide series of the periodic table. Uranium is weakly radioactive because all isotopes of uranium are unstable, with half-lives varying between 159,200 years and 4.5 billion years. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten.
Lutetium is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earths.
Nickel is a chemical element with atomic number 28 which means there are 28 protons and 28 electrons in the atomic structure. The chemical symbol for Nickel is Ni.Nickel is a silvery-white lustrous metal with a slight golden tinge. Nickel belongs to the transition metals and is hard and ductile.Nickel – PropertiesElementNickelAtomic Number28SymbolNiElement CategoryTransition MetalPhase at STPSolidAtomic Mass [amu]58.6934Density at STP [g/cm3]8.908Electron Configuration[Ar] 3d8 4s2Possible Oxidation States+2,3Electron Affinity [kJ/mol]112Electronegativity [Pauling scale]1.911st Ionization Energy [eV]7.6398Year of Discovery1751DiscovererCronstedt, Alex FredrikThermal propertiesMelting Point [Celsius scale]1455Boiling Point [Celsius scale]2730Thermal Expansion µm/(m·K)13.4Thermal Conductivity [W/m K]90.7Specific Heat [J/g K]0.44Heat of Fusion [kJ/mol]17.47Heat of Vaporization [kJ/mol]370.4Atomic Number of NickelNickel is a chemical element with atomic number 28 which means there are 28 protons and 28 electrons in the atomic structure. The chemical symbol for Nickel is Ni.The atom consist of a small but massive nucleus surrounded by a cloud of rapidly moving electrons. The nucleus is composed of protons and neutrons. Total number of protons in the nucleus is called the atomic number of the atom and is given the symbol Z. The total electrical charge of the nucleus is therefore +Ze, where e (elementary charge) equals to 1,602 x 10-19 coulombs. In a neutral atom there are as many electrons as protons moving about nucleus. It is the electrons that are responsible for the chemical bavavior of atoms, and which identify the various chemical elements.See also: Atomic Number – Does it conserve in a nuclear reaction?Atomic Number and Chemical PropertiesEvery solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.Density of NickelDensity of Nickel is 8.908g/cm3.Typical densities of various substances are at atmospheric pressure.Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides.
Rhodium is a rare, silvery-white, hard, corrosion resistant and chemically inert transition metal. It is a noble metal and a member of the platinum group.
The density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
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Indium is a post-transition metal that makes up 0.21 parts per million of the Earth’s crust. Very soft and malleable, indium has a melting point higher than sodium and gallium, but lower than lithium and tin. Chemically, indium is similar to gallium and thallium.
Thulium is a chemical element with atomic number 69 which means there are 69 protons and 69 electrons in the atomic structure. The chemical symbol for Thulium is Tm.Thulium is an easily workable metal with a bright silvery-gray luster. It is fairly soft and slowly tarnishes in air. Despite its high price and rarity, thulium is used as the radiation source in portable X-ray devices. Thulium is the thirteenth and third-last element in the lanthanide series.
Bismuth is a chemical element with atomic number 83 which means there are 83 protons and 83 electrons in the atomic structure. The chemical symbol for Bismuth is Bi.Bismuth is a brittle metal with a silvery white color when freshly produced, but surface oxidation can give it a pink tinge. Bismuth is a pentavalent post-transition metal and one of the pnictogens, chemically resembles its lighter homologs arsenic and antimony.
Fluorine is the lightest halogen and exists as a highly toxic pale yellow diatomic gas at standard conditions. As the most electronegative element, it is extremely reactive: almost all other elements, including some noble gases, form compounds with fluorine.
See also: Atomic Number – Does it conserve in a nuclear reaction?Atomic Number and Chemical PropertiesEvery solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.Density of NickelDensity of Nickel is 8.908g/cm3.Typical densities of various substances are at atmospheric pressure.Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:ρ = m/VIn words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).Density – Atomic Mass and Atomic Number DensitySince the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance, it is obvious, the density of a substance strongly depends on its atomic mass and also on the atomic number density (N; atoms/cm3),Atomic Weight. The atomic mass is carried by the atomic nucleus, which occupies only about 10-12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. Therefore it is determined by the mass number (number of protons and neutrons).Atomic Number Density. The atomic number density (N; atoms/cm3), which is associated with atomic radii, is the number of atoms of a given type per unit volume (V; cm3) of the material. The atomic number density (N; atoms/cm3) of a pure material having atomic or molecular weight (M; grams/mol) and the material density (⍴; gram/cm3) is easily computed from the following equation using Avogadro’s number (NA = 6.022×1023 atoms or molecules per mole): Since nucleons (protons and neutrons) make up most of the mass of ordinary atoms, the density of normal matter tends to be limited by how closely we can pack these nucleons and depends on the internal atomic structure of a substance. The densest material found on earth is the metal osmium, but its density pales by comparison to the densities of exotic astronomical objects such as white dwarf stars and neutron stars.If we include man made elements, the densest so far is Hassium. Hassium is a chemical element with symbol Hs and atomic number 108. It is a synthetic element (first synthesised at Hasse in Germany) and radioactive. The most stable known isotope, 269Hs, has a half-life of approximately 9.7 seconds. It has an estimated density of 40.7 x 103 kg/m3. The density of Hassium results from its high atomic weight and from the significant decrease in ionic radii of the elements in the lanthanide series, known as lanthanide and actinide contraction.Density – Pressure and TemperatureThe density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Most materials expand when their temperatures increase. Rising temperatures make the liquid expand in a liquid-in-tube thermometer and bend bimetallic strips. As a result of this expansion, the density of most materials decreases. This effect is caused by a decrease in the atomic number density. This dependence is usually expressed by the coefficient of linear or volume expansion.Increasing the pressure on an material (especially for liquids or gases) decreases the volume of the object and thus increases its density via the atomic number density. Compressibility (also known as the coefficient of compressibility is a measure of the relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.See also: What is DensitySee also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). These have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.
Electron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Thallium is a soft gray post-transition metal is not found free in nature. Commercially, thallium is produced as a byproduct from refining of heavy metal sulfide ores. Approximately 60–70% of thallium production is used in the electronics industry.
Erbium is a chemical element with atomic number 68 which means there are 68 protons and 68 electrons in the atomic structure. The chemical symbol for Erbium is Er.Erbium is a silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare earth element, originally found in the gadolinite mine in Ytterby in Sweden.
To use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Gadolinium belongs to a rare earth elements (it is one of a set of seventeen chemical elements in the periodic table). In nuclear industry gadolinium is commonly used as a neutron absorber due to very high neutron absorbtion cross-section of two isotopes 155Gd and 157Gd. In fact their absorption cross-sections are the highest among all stable isotopes.
Oxygen is a chemical element with atomic number 8 which means there are 8 protons and 8 electrons in the atomic structure. The chemical symbol for Oxygen is O.Oxygen is a colourless, odourless reactive gas, the chemical element of atomic number 8 and the life-supporting component of the air. It is a member of the chalcogen group on the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. By mass, oxygen is the third-most abundant element in the universe, after hydrogen and helium.
Ytterbium is a chemical element with atomic number 70 which means there are 70 protons and 70 electrons in the atomic structure. The chemical symbol for Ytterbium is Yb.Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides.
Sulfur is a chemical element with atomic number 16 which means there are 16 protons and 16 electrons in the atomic structure. The chemical symbol for Sulfur is S.Sulfur is abundant, multivalent, and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow crystalline solid at room temperature. Chemically, sulfur reacts with all elements except for gold, platinum, iridium, tellurium, and the noble gases.
Electron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid.
See also: Densest Materials of the EarthElectron Configuration and Oxidation States of NickelElectron configuration of Nickel is [Ar] 3d8 4s2.Possible oxidation states are +2,3.Electron ConfigurationThe periodic table is a tabular display of the chemical elements organized on the basis of their atomic numbers, electron configurations, and chemical properties. The electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. Knowledge of the electron configuration of different atoms is useful in understanding the structure of the periodic table of elements.Every solid, liquid, gas, and plasma is composed of neutral or ionized atoms. The chemical properties of the atom are determined by the number of protons, in fact, by number and arrangement of electrons. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.It is the Pauli exclusion principle that requires the electrons in an atom to occupy different energy levels instead of them all condensing in the ground state. The ordering of the electrons in the ground state of multielectron atoms, starts with the lowest energy state (ground state) and moves progressively from there up the energy scale until each of the atom’s electrons has been assigned a unique set of quantum numbers. This fact has key implications for the building up of the periodic table of elements.The first two columns on the left side of the periodic table are where the s subshells are being occupied. Because of this, the first two rows of the periodic table are labeled the s block. Similarly, the p block are the right-most six columns of the periodic table, the d block is the middle 10 columns of the periodic table, while the f block is the 14-column section that is normally depicted as detached from the main body of the periodic table. It could be part of the main body, but then the periodic table would be rather long and cumbersome.For atoms with many electrons, this notation can become lengthy and so an abbreviated notation is used. The electron configuration can be visualized as the core electrons, equivalent to the noble gas of the preceding period, and the valence electrons (e.g. [Xe] 6s2 for barium).Oxidation StatesOxidation states are typically represented by integers which may be positive, zero, or negative. Most elements have more than one possible oxidation state. For example, carbon has nine possible integer oxidation states from −4 to +4.The current IUPAC Gold Book definition of oxidation state is:“Oxidation state of an atom is the charge of this atom after ionic approximation of its heteronuclear bonds…”and the term oxidation number is nearly synonymous. An element that is not combined with any other different elements has an oxidation state of 0. Oxidation state 0 occurs for all elements – it is simply the element in its elemental form. An atom of an element in a compound will have a positive oxidation state if it has had electrons removed. Similarly, adding electrons results in a negative oxidation state. We have also distinguish between the possible and common oxidation states of every element. For example, silicon has nine possible integer oxidation states from −4 to +4, but only -4, 0 and +4 are common oxidation states.Electron Affinity and Electronegativity of NickelElectron affinity of Nickel is 112 kJ/mol.Electronegativity of Nickel is 1.91.Electron AffinityIn chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.X + e– → X– + energy Affinity = – ∆HIn other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.An atom of Nickel in the gas phase, for example, gives off energy when it gains an electron to form an ion of Nickel.Ni + e– → Ni– – ∆H = Affinity = 112 kJ/molTo use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.Electron affinity can be either positive or negative value. The greater the negative value, the more stable the anion is. Although affinity varies greatly across the periodic table, some patterns emerge. Generally, the elements on the right side of the periodic table will have large negative electron affinity. The electron affinities will become less negative as you go from the top to the bottom of the periodic table. However, nitrogen, oxygen, and fluorine do not follow this trend. Moreover, nonmetals have more positive affinity than metals. Atoms whose anions are more stable than neutral atoms have a greater affinity. Chlorine most strongly attracts extra electrons, while neon most weakly attracts an extra electron.Affinities of Non metals vs. Affinities of MetalsMetals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.ElectronegativityElectronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.The electronegativity of Nickel is: χ = 1.91In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it. The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7. Electronegativity is related with ionization energy and electron affinity. Electrons with low ionization energies have low electronegativities because their nuclei do not exert a strong attractive force on electrons. Elements with high ionization energies have high electronegativities due to the strong pull exerted by the positive nucleus on the negative electrons. Therefore the electronegativity is greatest at the top-right of the periodic table and decreases toward the bottom-left.Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
In general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.
Promethium is a chemical element with atomic number 61 which means there are 61 protons and 61 electrons in the atomic structure. The chemical symbol for Promethium is Pm.Promethium is one of only two such elements that are followed in the periodic table by elements with stable forms. All of its isotopes are radioactive. In nuclear reactors, promethium equilibrium exists in power operation. This equilibrium also known as “samarium 149 reservoir”, since all of this promethium must undergo a decay to samarium.
Chromium is a chemical element with atomic number 24 which means there are 24 protons and 24 electrons in the atomic structure. The chemical symbol for Chromium is Cr.Chromium is a steely-grey, lustrous, hard and brittle metal4 which takes a high polish, resists tarnishing, and has a high melting point. A major development was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel.
It is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. Carbon is one of the few elements known since antiquity. Carbon is the 15th most abundant element in the Earth’s crust, and the fourth most abundant element in the universe by mass after hydrogen, helium, and oxygen.
Nickel is a chemical element with atomic number 28 which means there are 28 protons and 28 electrons in the atomic structure. The chemical symbol for Nickel is Ni.
Francium is an alkali metal, that has one valence electron. Francium is the second-least electronegative element, behind only caesium, and is the second rarest naturally occurring element (after astatine). Francium is a highly radioactive metal that decays into astatine, radium, and radon.
Astatine is the rarest naturally occurring element on the Earth’s crust. It occurs on Earth as the decay product of various heavier elements. The bulk properties of astatine are not known with any certainty.
Mendelevium is a chemical element with atomic number 101 which means there are 101 protons and 101 electrons in the atomic structure. The chemical symbol for Mendelevium is Md.Mendelevium is a metallic radioactive transuranic element in the actinide series, it is the first element that currently cannot be produced in macroscopic quantities.
Terbium is a silvery-white, rare earth metal that is malleable, ductile, and soft enough to be cut with a knife. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas.
Rubidium is a chemical element with atomic number 37 which means there are 37 protons and 37 electrons in the atomic structure. The chemical symbol for Rubidium is Rb.Rubidium is a soft, silvery-white metallic element of the alkali metal group, with an atomic mass of 85.4678. Elemental rubidium is highly reactive, with properties similar to those of other alkali metals, including rapid oxidation in air.
Nickel – Melting Point and Boiling PointMelting point of Nickel is 1455°C.Boiling point of Nickel is 2730°C.Note that, these points are associated with the standard atmospheric pressure.Boiling PointIn general, boiling is a phase change of a substance from the liquid to the gas phase. The boiling point of a substance is the temperature at which this phase change (boiling or vaporization) occurs. The temperature at which vaporization (boiling) starts to occur for a given pressure is also known as the saturation temperature and at this conditions a mixture of vapor and liquid can exist together. The liquid can be said to be saturated with thermal energy. Any addition of thermal energy results in a phase transition. At the boiling point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the liquid is the more stable state of the two, whereas above the gaseous form is preferred. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.As can be seen, the boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100°C (212°F) at sea level, but at 93.4°C (200.1°F) at 1900 metres (6,233 ft) altitude. On the other hand, water boils at 350°C (662°F) at 16.5 MPa (typical pressure of PWRs).In the periodic table of elements, the element with the lowest boiling point is helium. Both the boiling points of rhenium and tungsten exceed 5000 K at standard pressure. Since it is difficult to measure extreme temperatures precisely without bias, both have been cited in the literature as having the higher boiling point.Melting PointIn general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. At the melting point the two phases of a substance, liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the melting point, the solid is the more stable state of the two, whereas above the liquid form is preferred. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.See also: Melting Point DepressionThe first theory explaining mechanism of melting in the bulk was proposed by Lindemann, who used vibration of atoms in the crystal to explain the melting transition. Solids are similar to liquids in that both are condensed states, with particles that are far closer together than those of a gas. The atoms in a solid are tightly bound to each other, either in a regular geometric lattice (crystalline solids, which include metals and ordinary ice) or irregularly (an amorphous solid such as common window glass), and are typically low in energy. The motion of individual atoms, ions, or molecules in a solid is restricted to vibrational motion about a fixed point. As a solid is heated, its particles vibrate more rapidly as the solid absorbs kinetic energy. At some point the amplitude of vibration becomes so large that the atoms start to invade the space of their nearest neighbors and disturb them and the melting process initiates. The melting point is the temperature at which the disruptive vibrations of the particles of the solid overcome the attractive forces operating within the solid.As with boiling points, the melting point of a solid is dependent on the strength of those attractive forces. For example, sodium chloride (NaCl) is an ionic compound that consists of a multitude of strong ionic bonds. Sodium chloride melts at 801°C. On the other hand, ice (solid H2O) is a molecular compound whose molecules are held together by hydrogen bonds, which is effectively a strong example of an interaction between two permanent dipoles. Though hydrogen bonds are the strongest of the intermolecular forces, the strength of hydrogen bonds is much less than that of ionic bonds. The melting point of ice is 0 °C.Covalent bonds often result in the formation of small collections of better-connected atoms called molecules, which in solids and liquids are bound to other molecules by forces that are often much weaker than the covalent bonds that hold the molecules internally together. Such weak intermolecular bonds give organic molecular substances, such as waxes and oils, their soft bulk character, and their low melting points (in liquids, molecules must cease most structured or oriented contact with each other). Nickel – Crystal StructureA possible crystal structure of Nickel is face-centered cubic structure.In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.The three most common basic crystal patterns are:Body-centered Cubic. In a body-centered cubic (BCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the body center of the cube. In a body-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (1 center atom × 1) = 2 atoms. The packing is more efficient (68%) than simple cubic and the structure is a common one for alkali metals and early transition metals. Metals containing BCC structures include ferrite, chromium, vanadium, molybdenum, and tungsten. These metals possess high strength and low ductility.Face-centered Cubic.In a face-centered cubic (FCC) arrangement of atoms, the unit cell consists of eight atoms at the corners of a cube and one atom at the center of each of the faces of the cube. In a face-centered cubic arrangement, a unit cell contains (8 corner atoms × ⅛) + (6 face atoms × ½) = 4 atoms. This structure, along with its hexagonal relative (hcp), has the most efficient packing (74%). Metals containing FCC structures include austenite, aluminum, copper, lead, silver, gold, nickel, platinum, and thorium. These metals possess low strength and high ductility.Hexagonal Close-packed. In a hexagonal close-packed (HCP) arrangement of atoms, the unit cell consists of three layers of atoms. The top and bottom layers contain six atoms at the corners of a hexagon and one atom at the center of each hexagon. The middle layer contains three atoms nestled between the atoms of the top and bottom layers, hence, the name close-packed. Hexagonal close packed (hcp) is one of the two simple types of atomic packing with the highest density, the other being the face centered cubic (fcc). However, unlike the fcc, it is not a Bravais lattice as there are two nonequivalent sets of lattice points. Metals containing HCP structures include beryllium, magnesium, zinc, cadmium, cobalt, thallium, and zirconium. HCP metals are not as ductile as FCC metals.–
Vanadium is a hard, silvery grey, ductile, and malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation) stabilizes the free metal somewhat against further oxidation.