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Ovčačíková, H., Tokarský, J., Maierová, P. et al. Effect of Mass Ratio and Milling on Compressive Strength and Corrosion Resistance of Blast-Furnace Slag/Fly Ash Geopolymer Activated by Solid Alkali Activator. J. Sustain. Metall. 8, 1961–1974 (2022). https://doi.org/10.1007/s40831-022-00618-5
Chaparro WA, Ruiz JHB, de Jesús Torres Gómez R (2012) Corrosion of reinforcing bars embedded in alkali-activated slag concrete subjected to chloride attack. Mater Res 15(1):57–62. https://doi.org/10.1590/S1516-14392011005000096
Bakharev T, Sanjayana JG, Chengb YB (2002) Sulfate attack on alkali-activated slag concrete. Cem Concr Res 32:211–216. https://doi.org/10.1016/S0008-8846(01)00659-7
High-speed, high-efficiency grade with great high-temperature strength, which realises excellent wear resistance in high-efficiency machining
Hitesh, Wattal R, Surabhi L (2021) Development and characterization of coal fly ash through low-energy ball milling. Mater Today Proc 47(11):2970–2975. https://doi.org/10.1016/j.matpr.2021.05.204
Ismail I, Bernal AS, Provis JL, Nicolas SR, Hamdan S, Van Deventer JSJ (2014) Modification of phase evolution in alkali-activated blast furnace slag by the incorporation of fly ash. Cem Concr Compos 45:125–135. https://doi.org/10.1016/j.cemconcomp.2013.09.006
100% diamond that directly binds nano-order diamond particles with high strength. Demonstrates optimum wear and fracture resistance as well as the best edge sharpness
Pacheco-Torgal F, Castro-Gomes J, Jalali S (2008) Alkali-activated binders: a review: Part 1. Historical background, terminology, reaction mechanisms and hydration products. Constr Build Mater 22(7):1305–1314. https://doi.org/10.1016/j.conbuildmat.2007.10.015
Hajimohammadi A, van Deventer JSJ (2017) Characterisation of one-part geopolymer binders made from fly ash. Waste Biomass Valoriz 8:225–233. https://doi.org/10.1007/s12649-016-9582-5
Bernal SA, Rodriguez ED, de Gutierrez RM, Provis JL (2012) Performance of alkali-activated slag mortars exposed to acids. J Adv Cem Based Mater 1(3):138–151. https://doi.org/10.1080/21650373.2012.747235
European Norm EN 196-6: Methods of testing cement—Part 6: determination of fineness, Czech Office for Standards, Metrology and Testing, Czech Republic, 2019
Hany E, Fouad N, Abdel-Wahab M, Sadek E (2020) Compressive strength of mortars incorporating alkali-activated materials as partial or full replacement of cement. Constr Build Mater 261:120518. https://doi.org/10.1016/j.conbuildmat.2020.120518
High-speed, high-efficiency grade with great high-temperature strength, which realises excellent wear resistance in high-efficiency machining
Employs Brilliant Coat PVD coating with excellent lubricity to provide better wear resistance and consistent surface finishes in low-speed cutting applications such as machining of small products or low carbon steel
Angulo-Ramírez DE, Valencia-Saavedra WG, Mejía de Gutiérrez R (2020) Alkali-activated concretes based on fly ash and blast furnace slag: Compressive strength, water absorption and chloride permeability. Ingeniería e Investigación 40(2):72–80. https://doi.org/10.15446/ing.investig.v40n2.83893
Petrakis E, Karmali V, Bartzas G, Komnitsas K (2019) Grinding kinetics of slag and effect of final particle size on the compressive strength of alkali activated materials. Minerals 9(11):714. https://doi.org/10.3390/min9110714
Alrefaei Y, Wang YS, Dai JG (2021) Effect of mixing method on the performance of alkali-activated fly ash/slag pastes along with polycarboxylate admixture. Cem Concr Compos 117:103917. https://doi.org/10.1016/j.cemconcomp.2020.103917
Development of crater damage is suppressed by controlling the orientation of the alumina crystal grains. Achieves long, stable tool life during high-speed and high feed cutting
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A new cermet substrate with excellent thermal conductivity is used to achieve outstanding thermal crack resistance. Also uses Brilliant Coat, which has excellent lubricity
Huseien GF, Mohd Sam AR, Alyousef R (2020) Texture, morphology and strength performance of self-compacting alkali-activated concrete: role of fly ash as GBFS replacement. Constr Build Mater 270:121368. https://doi.org/10.1016/j.conbuildmat.2020.121368
Rodríguez E, Bernal S, de Gutiérrez RM, Puertas F (2008) Alternative concrete based on alkali-activated slag. Mater Constr 58(291):53–67. https://doi.org/10.3989/mc.2008.v58.i291.104
Kumar S, Kumar R, Bandopadhyay A, Alex TC, Kumar BR, Das SK, Mehrotra SP (2008) Mechanical activation of granulated blast furnace slag and its effect on the properties and structure of portland slag cement. Cem Concr Compos 30:679–685. https://doi.org/10.1016/j.cemconcomp.2008.05.005
High-precision grade realizing long tool life with excellent surface roughness and stable machining. Maintains excellent surface roughness thanks to a high notch-wear resistant coating and tough CBN substrate
Zhang J, Shi C, Zhang Z, Ou Z (2017) Durability of alkali-activated materials in aggressive environments: a review on recent studies. Constr Build Mater 152:598–613. https://doi.org/10.1016/j.conbuildmat.2017.07.027
Hassan A, Arif M, Shariq M (2019) Use of geopolymer concrete for a cleaner and sustainable environment—a review of mechanical properties and microstructure. J Clean Prod 223:704–728. https://doi.org/10.1016/j.jclepro.2019.03.051
Alumina coating with even higher strength balances outstanding stability and wear resistance in mill-scale work on forged material. Gold-colored coating makes used corners easily identifiable
Duxson P, Provis JL (2008) Designing precursors for geopolymer cements. J Am Ceram Soc 91(12):3864–3869. https://doi.org/10.1111/j.1551-2916.2008.02787.x
High-hardness cermet with outstanding wear resistance and toughness. Realises high dimensional accuracy for continuous steel machining or finishing of powdered metal or cast iron
Our 1st recommended grade for turning exotic alloys as it realises stable tool life with high-speed, high-efficiency machining
General-purpose grade with excellent wear resistance, fracture resistance, and thermal shock resistance, suitable for machining of cast iron and exotic alloys
Kanti P, Sharma KV, Ramachandra CG, Minea AA (2020) Effect of ball milling on the thermal conductivity and viscosity of Indian coal fly ash nanofluid. Heat Transf 49(8):4475–4490. https://doi.org/10.1002/htj.21836
Fly ash and granulated blast-furnace slag can be considered "multifunctional waste." This study is focused on properties of a non-cement binder prepared from slag and fly ash activated by solid alkali activator. Fly ash was milled (2.5, 5.0, and 7.5 min) in order to increase its reactivity, and particle size distribution, specific surface area, and grain morphology were determined for all milled FA samples. Two GBFS + FA mixtures (70:30 and 85:15 w/w) were studied. Prepared mixtures were activated by solid alkali activator (Na2SiO3). Optimal weight ratios were calculated for CaO, SiO2, and Al2O3 components. Properties of the mixtures were studied in dependence on the GBFS:FA mass ratio and FA milling time (0–7.5 min). After 2 and 28 days of hydration, compressive strength of all mixtures exceeded 20 and 60 MPa, respectively. The 85:15 ratio led to generally higher compressive strength 108.3 MPa was reached after 90 days using FA milled for 7.5 min. Corrosion resistance was tested by exposing mixtures to distilled water, 0.5% HCl, and 3% Na2SO4 for 65 days, and evaluated by measuring changes in CS. Also the corrosion resistance was found higher (Na2SO4) than and comparable (HCl, water) to the 70:30 ratio. This study aims to show that GBFS + FA mixtures (70:30 and 85:15 w/w) activated by solid Na2SiO3 can achieve high CS and good corrosion resistance.
European Norm EN 15167-1: Ground granulated blast furnace slag for use in concrete, mortar and grout-Part 1: definitions, specifications and conformity criteria, Czech Office for Standards, Metrology and Testing, Czech Republic, 2006
Chi M, Huang R (2013) Binding mechanism and properties of alkali-activated fly ash/slag mortars. Constr Build Mater 40:291–298. https://doi.org/10.1016/j.conbuildmat.2012.11.003
High-hardness cermet with outstanding wear resistance and toughness. Realises high dimensional accuracy for continuous steel machining or finishing of powdered metal or cast iron
A general-purpose cermet made from hard grains with different grain sizes, delivering functionality that provides an excellent balance of wear resistance and toughness, along with good surface finish quality
This work was supported by Ministry of Education, Youth and Sports of the Czech Republic via the “Institute of Environmental Technology—Excellent Research” project [Grant Number CZ.02.1.01/0.0/0.0/16_019/0000853]; the “Research on the management of waste, materials and other products of metallurgy and related sectors” project [Grant Number CZ.02.1.01/0.0/0.0/17_049/0008426]; and the SGS projects [Grant Numbers SP2022/13 and SP2022/68].
Department of Thermal Engineering, Faculty of Materials Science and Technology, Institute of Environmental Technology, CEET, VSB-Technical University of Ostrava, 17. Listopadu 2172/15, 708 00, Ostrava, Czech Republic
Tang XY, Xiao J, Chen F (2006) Effect and research progress of acid deposition on concrete durability. Mater Rev 20(10):97–101. https://doi.org/10.1016/j.eng.2019.08.019
Oderji SY, Chen B, Ahmad MR, Shah SFA (2009) Fresh and hardened properties of one-part fly ash-based geopolymer binders cured at room temperature: effect of slag and alkali activators. J Clean Prod 225:1–10. https://doi.org/10.1016/j.jclepro.2019.03.290
High-hardness cermet with outstanding wear resistance and toughness. Realises high dimensional accuracy for continuous steel machining or finishing of powdered metal or cast iron
Wang KT, Du LQ, Lv XS, He Y, Cui XM (2017) Preparation of drying powder inorganic polymer cement based on alkali-activated slag technology. Powder Technol 312:204–209. https://doi.org/10.1016/j.powtec.2017.02.036
Kumar S, Kumar R, Mehrotra SP (2010) Influence of granulated blast furnace slag on the reaction, structure and properties of fly ash based geopolymer. J Mater Sci 45(3):607–615. https://doi.org/10.1007/s10853-009-3934-5
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Chindaprasirt P, Jaturapitakkul C, Sinsiri T (2005) Effect of fly ash fineness on compressive strength and pore size of blended cement paste. Cem Concr Compos 27:425–428. https://doi.org/10.1016/j.cemconcomp.2004.07.003
Komljenović M, Baščarević Z, Marjanović N, Miladinović Z, Petrović R (2015) The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers. Constr Build Mater 94:361–370. https://doi.org/10.1016/j.conbuildmat.2015.07.014
European Norm EN 1927-5: Monolithic (unshaped) refractory products—Part 5: preparation and treatment of the test pieces, Czech Office for Standards, Metrology and Testing, Czech Republic, 2013
Temuujin J, Williams RP, Van Riessen A (2009) Effect of mechanical activation of fly ash on the properties of geopolymer cured at ambient temperature. J Mater Process Technol 209(12–13):5276–5280. https://doi.org/10.1016/j.jmatprotec.2009.03.016
Fernández-Jiménez A, Palomo A, Criado M (2005) Microstructure development of alkali-activated fly ash cement: a descriptive model. Cem Concr Res 35(6):1204–1209. https://doi.org/10.3989/mc.2006.v56.i281.92
Employs a new PVD coating, and a dedicated tough carbide substrate. High-quality cutting edge grade suppresses adhesion and micro-chipping, realizing excellent machined surface quality
European Norm EN 196-1: Methods of testing cement. Part 1: determination of strength, Czech Office for Standards, Metrology and Testing, Czech Republic, 2016
Wang A, Zheng Y, Zhang Z, Liu K, Li Y, Shi L, Sun D (2020) The durability of alkali-activated materials in comparison with ordinary Portland cements and concretes: a review. Engineering 6(6):695–706. https://doi.org/10.1016/j.eng.2019.08.019
Kumar R, Kumar S, Mehrotra SP (2007) Towards sustainable solutions for fly ash through mechanical activation. Resour Conserv Recycl 52:157–159. https://doi.org/10.1016/j.resconrec.2007.06.007
For high-speed machining, BN1000 provides the highest wear resistance of all uncoated SUMIBORON grades, improving fracture resistance while maintaining an emphasis on wear resistance
Huseien GF, Mirza J, Ismail M, Hussin MW (2016) Influence of different curing temperatures and alkali activators on properties of GBFS geopolymer mortars containing fly ash and palm-oil fuel ash. Constr Build Mater 125:1229–1240. https://doi.org/10.1016/j.conbuildmat.2016.08.153
Pangdaeng S, Phoo-ngernkham T, Sata V, Chindaprasirt P (2014) Influence of curing conditions on properties of high calcium fly ash geopolymer containing Portland cement as additive. Mater Des 53:269–274. https://doi.org/10.1016/j.matdes.2013.07.018
Luukkonen T, Abdollahnejad Z, Yliniemi Y, Kinnunen P, Illikainen M (2014) One-part alkali-activated materials: a review. Cem Concr Res 103:21–34. https://doi.org/10.1016/j.cemconres.2017.10.001
Komljenović M, Baščarević Z, Bradić V (2010) Mechanical and microstructural properties of alkali-activated fly ash geopolymers. J Hazard Mater 181(1–3):35–42. https://doi.org/10.1016/j.jhazmat.2010.04.064
Guo X, Shi H, Dick WA (2010) Compressive strength and microstructural characteristics of class C fly ash geopolymer. Cem Concr Compos 32(2):142–147. https://doi.org/10.1016/j.cemconcomp.2009.11.003
Krivenko P (2017) Why alkaline activation—60 years of the theory and practice of alkali-activated materials. J Ceram Sci Technol 8(3):323–334. https://doi.org/10.4416/JCST2017-00042
Institute of Environmental Technology, CEET, Nanotechnology Centre, CEET, VSB-Technical University of Ostrava, 17. Listopadu 2172/15, 708 00, Ostrava, Czech Republic
ASTM C618-19, Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete, ASTM International, West Conshohocken, PA, (2019)
Our 1st recommended grade for turning steel. Surface smoothing technology significantly suppresses adhesion of work material components. Achieves long, stable tool life with various cutting speeds and work materials
Fernández-Jiménez A, Palomo A (2003) Characterisation of fly ashes. Potential React Alkaline Cem Fuel 82(18):2259–2265. https://doi.org/10.1016/S0016-2361(03)00194-7
Tensile stress removal of the coating layer greatly improves fracture resistance. Achieves long, stable tool life during heavy interrupted cutting
Vargas AS, Molin DC, Vilelac ACF, da Silva FJ, Pavão B, Veit H (2011) The effects of Na2O/SiO2 molar ratio, curing temperature and age on compressive strength, morphology and microstructure of alkali-activated fly ash-based geopolymers. Cem Concr Compos 33(6):653–660. https://doi.org/10.1016/j.cemconcomp.2011.03.006
Palomo A, Krivenko PV, Garcia-Lodeiro L, Kavalerova E, Maltseva O, Fernández-Jiménez A (2014) A review on alkaline activation: new analytical perspectives. Mater Construct. https://doi.org/10.3989/mc.2014.00314
Combines a high-hardness carbide substrate with excellent wear resistance and a new CVD coating with improved coating strength to achieve both excellent wear resistance and fracture resistance. Achieves long, stable tool life during high-speed cutting
Hossain MM, Karim MR, Hossain MK, Islam MN, Zain MFM (2015) Durability of mortar and concrete containing alkali-activated binder with pozzolans: a review. Constr Build Mater 93:95–109. https://doi.org/10.1016/j.conbuildmat.2015.05.094
A general-purpose cermet made from hard grains with different grain sizes, delivering functionality that provides an excellent balance of wear resistance and toughness, along with good surface finish quality
Chu YS, Davaabal B, Kim DS, Seo SK, Kim Y, Ruescher C, Temuujin J (2019) Reactivity of fly ashes milled in different milling devices. Rev Adv Mater Sci 58:179–188. https://doi.org/10.1515/rams-2019-0028
Tough grade for titanium machining with excellent fracture and thermal resistance. Perfect for interrupted cutting and mill-scaled work
Drastically improves reliability in the unstable cutting range, thanks to the excellent adhesion and peel-off resistance of the new PVD coating as well as the improved fracture resistance of the dedicated carbide substrate
Yazdi MA, Liebscher M, Hempel S, Yang J, Mechtcherine V (2018) Correlation of microstructural and mechanical properties of geopolymers produced from fly ash and slag at room temperature. Constr Build Mater 191:330–341. https://doi.org/10.1016/j.conbuildmat.2018.10.037
Superior fracture resistance, providing excellent stability in interrupted unstable cutting and when cutting mill-scaled work
Centre for Advanced Innovation Technology, VSB-Technical University of Ostrava, 17. Listopadu 2172/15, 708 00, Ostrava, Czech Republic
Puligilla S, Mondal P (2013) Role of slag in microstructural development and hardening of fly ash-slag geopolymer. Cem Concr Res 43:70–80. https://doi.org/10.1016/j.cemconres.2012.10.004
Our 1st recommended grade for turning of stainless steel, achieving long and stable machining. Drastically reduces the abnormal damage common in stainless steel machining, thanks to the improved coating strength and excellent adhesion
Yang B, Jang JG (2020) Environmentally benign production of one-part alkali-activated slag with calcined oyster shell as an activator. Constr Build Mater 257(2):119552. https://doi.org/10.1016/j.conbuildmat.2020.119552
Superior wear and plastic deformation resistant grade, that utilizes a high hardness carbide substrate coupled with the high hardness Super FF Coat for high speed to continuous turning of Cast Iron
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Achieves high-efficiency, improved machining accuracy, and long tool life in machining of exotic alloys such as titanium alloy and Co-Cr alloys
Rashad AM (2014) A comprehensive overview about the influence of different admixtures and additives on the properties of alkali-activated fly ash. Mater Des 53:1005–1025. https://doi.org/10.1016/j.matdes.2013.07.074
White SC, Case ED (1990) Characterization of fly ash from coal-fired power plants. J Mater Sci 25:5215–5219. https://doi.org/10.1007/BF00580153
High-density sintered material made of ultra-fine grain diamond that demonstrates optimum wear and fracture resistance and excellent edge sharpness
High-hardness cermet with outstanding wear resistance and toughness. Realises high dimensional accuracy for continuous steel machining or finishing of powdered metal or cast iron
Felekoğlu B, Türkel S, Kalyoncu H (2009) Optimization of fineness to maximize the strength activity of high-calcium ground fly ash—Portland cement composites. Constr Build Mater 23:2053–2061. https://doi.org/10.1016/j.conbuildmat.2008.08.024
Vlček J, Švrčinová R, Burda J, Topinková M, Klárová M, Ovčačíková H, Jančar D, Velička M (2016) Hydraulic properties of ladle slag. Metalurgija 55(3):399–402
Kumar S, Bandopadhyay A, Rajinikanth V, Alex TC, Kumar R (2004) Improved processing of blended cement through mechanical activation. J Mater Sci 39:3449–3452. https://doi.org/10.1023/B:JMSC.0000026948.85440.cc
Our 1st recommended grade for ductile cast iron. New high-adhesion, high-strength CVD coating realises both wear resistance and chipping resistance
Ononiwu NH, Ozoegwu CG, Akinribide OJ, Akinlabi ET (2021) Effect of particle size on the microstructure and distribution of fly ash for metal matrix composite applications. Mater Today Proc 44(1):1118–1123. https://doi.org/10.1016/j.matpr.2020.11.227
Huseien GF, Tahir MM, Mirza J, Ismail M, Shah KW, Asaad MA (2018) Effects of POFA replaced with FA on durability properties of GBFS included alkali activated mortars. Constr Build Mater 175:174–186. https://doi.org/10.1016/j.conbuildmat.2018.04.166
Li H, Chen Y, Cao Y, Liu G, Li B (2015) Comparative study on the characteristics of ball-milled coal fly ash. J Therm Anal Calorim 124:839–846. https://doi.org/10.1007/s10973-015-5160-5
Puertas F, de Gutiérrez R, Fernández-Jiménez A, Delvasto S, Maldonado J (2002) Alkaline cement mortars. Chemical resistance to sulfate and seawater attack. Mater Constr 52(267):55–71. https://doi.org/10.3989/mc.2002.v52.i267.326
Paul KT, Satpathy SK, Manna I, Chakraborty KK, Nando GB (2007) Preparation and characterization of nanostructured materials from fly ash: a waste from thermal power stations, by high energy ball milling. Nanoscale Res Lett 2:397–404. https://doi.org/10.1007/s11671-007-9074-4
General-purpose grade for titanium machining that features excellent wear and thermal resistance. For applications from roughing to finishing
Fernández-Jiménez A, Garcia-Lodeiro I, Maltseva O, Palomo A (2019) Mechanical-chemical activation of coal fly ashes: an effective way for recycling and make cementitious materials. Front Mater 6:51. https://doi.org/10.3389/fmats.2019.00051
Luukkonen T, Abdollahnejad Z, Yliniemi J, Kinnunen P, Illikainen M (2018) Comparison of alkali and silica sources in one-part alkali-activated blast furnace slag mortar. J Clean Prod 187:171–179. https://doi.org/10.1016/j.jclepro.2018.03.202
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1st recommended grade, balancing excellent wear resistance and fracture resistance in hardened steel machining.Along with a tough CBN substrate, the coating combines wear resistance and toughness to achieve long, stable tool life even in high-efficiency and interrupted machining
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High-speed, high-efficiency grade with great high-temperature strength, which realises excellent wear resistance in high-efficiency machining
Kubba Z, Huseien GF, Sam ARM, Shah KW, Asaad MA, Ismail M, Tahir MM, Mirza J (2018) Impact of curing temperatures and alkaline activators on compressive strengthand porosity of ternary blended geopolymer mortars. Case Stud Constr Mater 9:e00205. https://doi.org/10.1016/j.cscm.2018.e00205
Blanco F, Garcia MP, Ayla J, Mayoral G, Garcia MA (2006) The effect of mechanical and chemical activated fly ashes on mortar properties. Fuel 85:2018–2026. https://doi.org/10.1016/j.fuel.2006.03.031